The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
The specific gravity of fixed air he found 1·57, that of common air
being 1.[186] Fixed air is incapable of supporting combustion, and
common air, when mixed with it, supports combustion a much shorter time
than when pure. A small wax taper burnt eighty seconds in a receiver
which held 180 ounce measures, when filled with common air only. The
same taper burnt fifty-one seconds in the same receiver when filled
with a mixture of one volume fixed air, and nineteen volumes of common
air. When the fixed air was 3-40ths of the whole volume the taper
burnt twenty-three seconds. When the fixed air was 1-10th, the taper
burnt eleven seconds. When it was 6-55ths or 1-9·16 of the whole
mixture, the taper would not burn at all.
[186] This I apprehend to be a little above the truth, the true
specific gravity of carbonic acid gas being 1·5277, that of air being
unity.
Mr. Cavendish was of opinion that more than one kind of fixed air was
given out by marble; in other words, that the elastic fluid emitted,
consisted of two different airs, one more absorbable by water than
the other. He drew his conclusion from the circumstance that after a
solution of potash had been exposed to a quantity of fixed air for
some time, it ceased to absorb any more; yet, if the residual portion
of air were thrown away and new fixed air substituted in its place, it
began to absorb again; but Mr. Dalton has since given a satisfactory
explanation of this seeming anomaly by showing that the absorbability
of fixed air in water is proportional to its purity, and that when
mixed with a great quantity of common air or any other gas not soluble
in water, it ceases to be sensibly absorbed.
Mr. Cavendish ascertained the quantity of fixed air contained in
marble, carbonate of ammonia, common pearlashes, and carbonate of
potash: but notwithstanding the care with which these experiments were
made they are of little value; because the proper precautions could not
be taken, in that infant state of chemical science, to have these salts
in a state of purity. The following were the results obtained by Mr.
Cavendish:
1000 grains of marble contained 408 grs. fixed air.
1000 -- carb. of ammonia 533 --
1000 -- pearlashes 284 --
1000 -- carb. of potash 423 --
Supposing the marble, carbonate of ammonia, and carbonate of potash, to
have been pure anhydrous simple salts, their composition would be
1000 grains of marble contain 440 grs. fixed air.
1000 -- carb. of ammonia 709·6 --
1000 -- carb. of potash 314·2 --
Bicarbonate of potash was first obtained by Dr. Black. Mr. Cavendish
formed the salt by dissolving pearlashes in water, and passing a
current of carbonic acid gas through the solution till it deposited
crystals. These crystals were not altered by exposure to the air, did
not deliquesce, and were soluble in about four times their weight of
cold water.
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