The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
Geber mentions three alums which he was in the habit of using; namely,
icy alum, or Rocca alum; Jamenous alum, or alum of Jameni, and feather
alum. _Rocca_, or _Edessa_, in Syria, is admitted to have been the
place where the first manufactory of alum was established; but at what
time, or by whom, is quite unknown: we know only that it must have
been posterior to the commencement of the Christian era, and prior to
the eighth century, when Geber wrote. Jameni must have been another
locality where, at the time of Geber, a manufactory of alum existed.
_Feather alum_ was undoubtedly one of the native impure varieties of
_alum_, known to the Greeks and Romans. Geber was in the habit of
distilling alum by a strong heat, and of preserving the water which
came over as a valuable menstruum. If alum be exposed to a red heat
in glass vessels, it will give out a portion of sulphuric acid: hence
water distilled from alum by Geber was probably a weak solution of
sulphuric acid, which would undoubtedly act powerfully as a solvent of
iron, and of the alkaline carbonates. It was probably in this way that
he used it.
6. Sulphate of iron or copperas, as it is called (_cuperosa_), in the
state of a crystalline salt, was well known to Geber, and appears in
his time to have been manufactured.
7. Baurach, or borax, is mentioned by him, but without any description
by which we can know whether or not it was our borax: the probability
is that it was. Both glass and borax were used by him when the oxides
of metals were reduced by him to the metallic state.
8. Vinegar was purified by him by distilling it over, and it was used
as a solvent in many of his processes.
9. Nitric acid was known to him by the name of _dissolving water_. He
prepared it by putting into an alembic one pound of sulphate of iron of
Cyprus, half a pound of saltpetre, and a quarter of a pound of alum of
Jameni: this mixture was distilled till every thing liquid was driven
over. He mentions the red fumes which make their appearance in the
alembic during the process.[122] This process, though not an economical
one, would certainly yield nitric acid; and it is remarkable, because
it is here that we find the first hint of the knowledge of chemists of
this most important acid, without which many chemical processes of the
utmost importance could not be performed at all.
[122] Invention of Verity, chap. 23.
10. This acid, thus prepared, he made use of to dissolve silver: the
solution was concentrated till the nitrate of silver was obtained by
him in a crystallized state. This process is thus described by him:
“Dissolve silver calcined in solutive water (_nitric acid_), as before;
which being done, coct it in a phial with a long neck, the orifice of
which must be left unstopped, for one day only, until a third part of
the water be consumed. This being effected, set it with its vessel in
a cold place, and then it is converted into small fusible stones, like
crystal.”[123]
[123] Ibid., chap. 21.
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