The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
11. He was in the habit also of dissolving sal ammoniac in this nitric
acid, and employing the solution, which was the aqua regia of the old
chemists, to dissolve gold.[124] He assures us that this aqua regia
would dissolve likewise sulphur and silver. The latter assertion is
erroneous. But sulphur is easily converted into sulphuric acid by the
action of aqua regia, and of course it disappears or dissolves.
[124] Ibid., chap. 23.
12. Corrosive sublimate is likewise described by Geber in a very
intelligible manner. His method of preparing it was as follows: “Take
of mercury one pound, of dried sulphate of iron two pounds, of alum
calcined one pound, of common salt half a pound, and of saltpetre a
quarter of a pound: incorporate altogether by trituration and sublime;
gather the white, dense, and ponderous portions which shall be found
about the sides of the vessel. If in the first sublimation you find it
turbid or unclean (which may happen by reason of your own negligence),
sublime a second time with the same fuses.”[125] Still more minute
directions are given in other parts of the work: we have even some
imperfect account of the properties of corrosive sublimate.
[125] Invention of Verity, chap. 8.
13. Corrosive sublimate is not the only preparation of mercury
mentioned by Geber. He informs us that when mercury is combined
with sulphur it assumes a red colour, and becomes cinnabar.[126] He
describes the affinities of mercury for the different metals. It
adheres easily to three metals; namely, lead, tin, and gold; to silver
with more difficulty. To copper with still more difficulty than to
silver; but to iron it unites in nowise unless by artifice.[127] This
is a tolerably accurate account of the matter. He says, that mercury is
the heaviest body in nature except gold, which is the only metal that
will sink in it.[128] Now this was true, applied to all the substances
known when Geber lived.
[126] Sum of Perfection, book i. part iii. chap. 4.
[127] Ibid., chap. 6.
[128] Ibid.
He gives an account of the method of forming the peroxide of mercury
by heat; that variety of it formerly distinguished by the name of _red
precipitati per se_. “Mercury,” he says, “is also coagulated by long
and constant retention in fire, in a glass vessel with a very long
neck and round belly; the orifice of the neck being kept open, that
the humidity may vanish thereby.”[129] He gives another process for
preparing this oxide, possible, perhaps, though certainly requiring
very cautious regulation of the fire. “Take,” says he, “of mercury
one pound, of vitriol (sulphate of iron) rubified two pounds, and of
saltpetre one pound. Mortify the mercury with these, and then sublime
it from rock alum and saltpetre in equal weights.”[130]
[129] Sum of Perfection, book i. part iv. chap. 16.
[130] Invention of Verity, chap. 10.
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