The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
I must acknowledge myself not quite satisfied with Berthollet's
reasoning on this subject. No doubt if two atoms of a body having a
weaker affinity, and one atom of a body having a stronger affinity,
were placed at equal distances from an atom of a third body, the
force of the two atoms might overcome that of the one atom. And it is
possible that such cases may occasionally occur: but such a balance
of distances must be rare and accidental. I cannot but think that all
the cases adduced by Berthollet are of a complicated nature, and admit
of an explanation independent of the efficacy of mass. And at any
rate, abundance of instances might be stated, in which mass appears to
have no preponderating effect whatever. Chemical decomposition is a
phenomenon of so complicated a nature, that it is more than doubtful
whether we are yet in possession of data sufficient to enable us to
analyze the process with accuracy.
Another opinion brought forward by Berthollet in his work was of a
startling nature, and occasioned a controversy between him and Proust
which was carried on for some years with great spirit, but with perfect
decorum and good manners on both sides. Berthollet affirmed that bodies
were capable of uniting with each other in all possible proportions,
and that there is no such thing as a definite compound, unless it
has been produced by some accidental circumstances, as insolubility,
volatility, &c. Thus every metal is capable of uniting with all
possible doses of oxygen. So that instead of one or two oxides of
every metal, an infinite number of oxides of each metal exist. Proust
affirmed that all compounds are definite. Iron, says he, unites with
oxygen only in two proportions; we have either a compound of 3·5 iron
and 1 oxygen, or of 3·5 iron and 1·5 oxygen. The first constitutes
the _black_, and the second the _red_ oxide of iron; and beside these
there is no other. Every one is now satisfied that Proust's view of
the subject was correct, and Berthollet's erroneous. But a better
opportunity will occur hereafter to explain this subject, or at least
to give the information respecting it which we at present possess.
Public-domain text, read in full here on John Shaqi.
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