The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Berthollet in this book points out the quantity of each base necessary
to neutralize a given weight of acid, and he considers the strength
of affinity as inversely that quantity. Now of all the bases known
when Berthollet wrote, ammonia is capable of saturating the greatest
quantity of acid. Hence he considered its affinity for acids as
stronger than that of any other base. Barytes, on the contrary,
saturates the smallest quantity of acid; therefore its affinity for
acids is smallest. Now ammonia is separated from acids by all the
other bases; while there is not one capable of separating barytes. It
is surprising that the notoriety of this fact did not induce him to
hesitate, before he came to so problematical a conclusion. Mr. Kirwan
had already considered the force of affinity as directly proportional
to the quantity of base necessary to saturate a given weight of acid.
When we consider the subject metaphysically, Berthollet's opinion is
most plausible; for it is surely natural to consider that body as the
strongest which produces the greatest effect. Now when we deprive an
acid of its properties, or neutralize it by adding a base, one would
be disposed to consider that base as acting with most energy, which
with the smallest quantity of matter is capable of producing a given
effect. This was the way that Berthollet reasoned. But if we attend
to the power which one base has of displacing another, we shall find
it very nearly proportional to the weight of it necessary to saturate
a given weight of acid; or, at least those bases act most powerfully
in displacing others of which the greatest quantity is necessary to
saturate a given weight of acid. Kirwan's opinion, therefore, was more
conformable to the order of decomposition. These two opposite views of
the subject show clearly that neither Kirwan nor Berthollet had the
smallest conception of the atomic theory; and, consequently, that the
allegation of Mr. Higgens, that he had explained the atomic theory
in his book on phlogiston, published in the year 1789, was not well
founded. Whether Berthollet had read that book I do not know, but there
can be no doubt that it was perused by Kirwan; who, however, did not
receive from it the smallest notions respecting the atomic theory. Had
he imbibed any such notions, he never would have considered chemical
affinity as capable of being measured by the weight of base capable of
neutralizing a given weight of acid.
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