The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
1. When a mineral is subjected to analysis, whatever care we take
to collect all the constituents, and to weigh them without losing
any portion whatever, it is generally found that the sum of the
constituents obtained fall a little short of the weight of the mineral
employed in the analysis. Thus, if we take 100 grains of any mineral,
and analyze it, the weights of all the constituents obtained added
together will rarely make up 100 grains, but generally somewhat
less; perhaps only 99, or even 98 grains. But some cases occur, when
the analysis of 100 grains of a mineral gives us constituents that
weigh, when added together, more than 100 grains; perhaps 105, or, in
some rare cases, as much as 110. It was the custom with Bergman, and
other analysts of his time, to consider this deficiency or surplus as
owing to errors in the analysis, and therefore to slur it over in the
statement of the analysis, by bringing the weight of the constituents,
by calculation, to amount exactly to 100 grains. Klaproth introduced
the method of stating the results exactly as he got them. He gives the
weight of mineral employed in all his analyses, and the weight of each
constituent extracted. These weights, added together, generally show a
loss, varying from two per cent. to a half per cent. This improvement
may appear at first sight trifling; yet I am persuaded that to it
we are indebted for most of the subsequent improvements introduced
into analytical chemistry. If the loss sustained was too great, it
was obvious either that the analysis had been badly performed, or
that the mineral contains some constituent which had been overlooked,
and not obtained. This laid him under the necessity of repeating the
analysis; and if the loss continued, he naturally looked out for some
constituent which his analysis had not enabled him to obtain. It was
in this way that he discovered the presence of potash in minerals; and
Dr. Kennedy afterwards, by following out his processes, discovered
soda as a constituent. It was in this way that water, phosphoric acid,
arsenic acid, fluoric acid, boracic acid, &c., were also found to exist
as constituents in various mineral bodies, which, but for the accurate
mode of notation introduced by Klaproth, would have been overlooked and
neglected.
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