The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
2. When Klaproth first began to analyze mineral bodies, he found
it extremely difficult to bring them into a state capable of being
dissolved in acids, without which an accurate analysis was impossible.
Accordingly corundum, adamantine spar, and the zircon, or hyacinth,
baffled his attempts for a considerable time, and induced him to
consider the earth of corundum as of a peculiar nature. He obviated
this difficulty by reducing the mineral to an extremely fine powder,
and, after digesting it in caustic potash ley till all the water was
dissipated, raising the temperature, and bringing the whole into a
state of fusion. This fusion must be performed in a silver crucible.
Corundum, and every other mineral which had remained insoluble after
fusion with an alkaline carbonate, was found to yield to this new
process. This was an improvement of considerable importance. All
those stony minerals which contain a notable proportion of silica, in
general become soluble after having been kept for some time in a state
of ignition with twice their weight of carbonate of soda. At that
temperature the silica of the mineral unites with the soda, and the
carbonic acid is expelled. But when the quantity of silica is small,
or when it is totally absent, heating with carbonate of soda does not
answer so well. With such minerals, caustic potash or soda may be
substituted with advantage; and there are some of them that cannot
be analyzed without having recourse to that agent. I have succeeded
in analyzing corundum and chrysoberyl, neither of which, when pure,
contain any silica, by simply heating them in carbonate of soda; but
the process does not succeed unless the minerals be reduced to an
exceedingly minute powder.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account