The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
To Professor Stromeyer we are likewise indebted for the discovery of
the new metal called _cadmium_; and the discovery does great credit
to his sagacity and analytical skill. He is inspector-general of the
apothecaries for the kingdom of Hanover. While discharging the duties
of his office at Hildesheim, in the year 1817, he found that the
carbonate of zinc had been substituted for the oxide of zinc, ordered
in the Hanoverian Pharmacopœia. This carbonate of zinc was manufactured
at Salzgitter. On inquiry he learned from Mr. Jost, who managed that
manufactory, that they had been obliged to substitute the carbonate
for the oxide of zinc, because the oxide had a yellow colour which
rendered it unsaleable. On examining this oxide, Stromeyer found
that it owed its yellow colour to the presence of a small quantity of
the oxide of a new metal, which he separated, reduced, and examined,
and to which he gave the name of _cadmium_, because it occurs usually
associated with zinc. The quantity of cadmium which he was able to
obtain from this oxide of zinc was but small. A fortunate circumstance,
however, supplied him with an additional quantity, and enabled him to
carry his examination of cadmium to a still greater length. During the
apothecaries' visitation in the state of Magdeburg, there was found,
in the possession of several apothecaries, a preparation of zinc
from Silesia, made in Hermann's laboratory at Schönebeck, which was
confiscated on the supposition that it contained arsenic, because its
solution gave a yellow precipitate with sulphuretted hydrogen, which
was considered as orpiment. This statement could not be indifferent
to Mr. Hermann, as it affected the credit of his manufactory;
especially as the medicinal counsellor, Roloff, who had assisted
at the visitation, had drawn up a statement of the circumstances
which occasioned the confiscation, and caused it to be published in
Hofeland's Medical Journal. He subjected the suspected oxide to a
careful examination; but he could not succeed in detecting any arsenic
in it. He then requested Roloff to repeat his experiments. This he
did; and now perceived that the precipitate, which he had taken for
orpiment, was not so in reality, but owed its existence to the presence
of another metallic oxide, different from arsenic and probably new.
Specimens of this oxide of zinc, and of the yellow precipitate, were
sent to Stromeyer for examination, who readily recognised the presence
of cadmium, and was able to extract from it a considerable quantity of
that metal.
It is now nine years since the first volume of the Untersuchungen was
published. All those who are interested in analytical chemistry are
anxious for the continuance of that admirable work. By this time he
must have collected ample materials for an additional volume; and it
could not but add considerably to a reputation already deservedly high.
Public-domain text, read in full here on John Shaqi.
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