The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Yet the minerals differ from each other in their hardness, specific
gravity, and in the shape of their crystals. Many attempts had been
made to account for this difference in characters between these two
minerals, but in vain. Mr. Holme showed that arragonite contained
about one per cent. of water, which is wanting in calcareous spar;
and that when arragonite is heated, it crumbles into powder, which is
not the case with calcareous spar. But it is not easy to conceive how
the addition of one per cent. of water should increase the specific
gravity and the hardness, and quite alter the shape of the crystals
of calcareous spar. Stromeyer made a vast number of experiments
upon arragonite, with very great care, and the result was, that the
arragonite from Bastenes, near Dax, in the department of Landes, and
likewise that from Molina, in Arragon, was a compound of
96 carbonate of lime
4 carbonate of strontian.
This amounts to about thirty-five atoms of carbonate of lime, and
one atom of carbonate of strontian. Now as the hardness and specific
gravity of carbonate of strontian is greater than that of carbonate of
lime, we can see a reason why arragonite should be heavier and harder
than calcareous spar. More late researches upon different varieties
of arragonite enabled him to ascertain that this mineral exists with
different proportions of carbonate of strontian. Some varieties contain
only 2 per cent., some only 1 per cent., and some only 0·75, or even
0·5 per cent.; but he found no specimen among the great number which
he analyzed totally destitute of carbonate of strontian. It is true
that Vauquelin afterwards examined several varieties in which he
could detect no strontian whatever; but as Vauquelin's mineralogical
knowledge was very deficient, it comes to be a question, whether the
minerals analyzed by him were really arragonites, or only varieties of
calcareous spar.
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