The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Volta, who repeated these experiments, explained them in a different
manner. According to him, the convulsions were produced by the passage
of a current of common electricity through the limb of the frog,
which was thrown into a state of convulsion merely in consequence of
its irritability. This irritability vanishes after the death of the
muscle; accordingly it is only while the principle of life remains that
the convulsions can be produced. Every metallic conductor, according
to him, possesses a certain electricity which is peculiar to it,
either positive or negative, though the quantity is so small, as to
be imperceptible, in the common state of the metal. But if a metal,
naturally positive, be placed in contact, while insulated, with a metal
naturally negative, the charge of electricity in both is increased by
induction, and becomes perceptible when the two metals are separated
and presented to a sufficiently delicate electrometer. Thus zinc is
naturally positive, and copper and silver naturally negative. If we
take two discs of copper and zinc, to the centre of each of which a
varnished glass handle is cemented, and after keeping them for a short
time in contact, separate them by the handles, and apply each to a
sufficiently delicate electrometer, we shall find that the zinc is
positive, and the silver or copper disc negative. When the silver and
copper are placed in contact while lying on the nerve and muscles of
the leg of a frog, the zinc becomes positive, and the silver negative,
by induction; but, as the animal substance is a conductor, this state
cannot continue: the two electricities pass through the conducting
muscles and nerve, and neutralize one another. And it is this current
which occasions the convulsions.
Such was Volta's simple explanation of the convulsions produced in
galvanic experiments in the limb of a frog. Galvani was far from
allowing the accuracy of it; and, in order to obviate the objection to
his reasoning advanced by Volta from the necessity of employing two
metals, he showed that the convulsions might, in certain cases, be
produced by one metal. Volta showed that a very small quantity of one
metal, either alloyed with, or merely in contact with another, were
capable of inducing the two electricities. But in order to prove in the
most unanswerable manner that the two electricities were induced when
two different metals were placed in contact, he contrived the following
piece of apparatus:
Public-domain text, read in full here on John Shaqi.
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