The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
He procured a number (say 50) of pieces of zinc, about the size of
a crown-piece, and as many pieces of copper, and thirdly, the same
number of pieces of card of the same size. The cards were steeped in
a solution of salt, so as to be moist. He lays upon the table a piece
of zinc, places over it a piece of copper, and then a piece of moist
card. Over the card is placed a second piece of zinc, then a piece
of copper, then a piece of wet card. In this way all the pieces are
piled upon each other in exactly the same order, namely, zinc, copper,
card; zinc, copper, card; zinc, copper, card. So that the lowest plate
is zinc and the uppermost is copper (for the last wet card may be
omitted). In this way there are fifty pairs of zinc and copper plates
in contact, each separated by a piece of wet card, which is a conductor
of electricity. If you now moisten a finger of each hand with water,
and apply one wet finger to the lowest zinc plate, and the other to the
highest copper plate, the moment the fingers come in contact with the
plates an electric shock is felt, the intensity of which increases with
the number of pairs of plates in the pile. This is what is called the
Galvanic, or rather the Voltaic pile. It was made known to the public
in a paper by Volta, inserted in the Philosophical Transactions for
1800. This pile was gradually improved, by substituting troughs, first
of baked wood, and afterwards of porcelain, divided into as many cells
as there were pairs of plates. The size of the plates was increased;
they were made square, and instead of all being in contact, it was
found sufficient if they were soldered together by means of metallic
slips rising from one side of each square. The two plates thus soldered
were slipped over the diaphragm separating the contiguous cells, so
that the zinc plate was in one cell and the copper in the other. Care
was taken that the pairs were introduced all looking one way, so that
a copper plate had always a zinc plate immediately opposite to it.
The cells were filled with conducting liquid: brine, or a solution of
salt in vinegar, or dilute muriatic, sulphuric, or nitric acid, might
be employed; but dilute nitric acid was found to answer best, and the
energy of the battery is directly proportional to the strength of the
nitric acid employed.
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