The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
If electricity be considered as consisting of two distinct fluids,
which attract each other with a force inversely, as the square of the
distance, while the particles of each fluid repel each other with a
force varying according to the same law, then we must conclude that
the atoms of each body are covered externally with a coating of some
one electric fluid to a greater or smaller extent. Oxygen and the
other supporters of combustion are covered with a coating of negative
electricity; while hydrogen, carbon, and the metals, are covered with
a coating of positive electricity. What is the cause of the adherence
of the electricity to these atoms we cannot explain. It is not owing to
an attraction similar to gravitation; for electricity never penetrates
into the interior of bodies, but spreads itself only on the surface,
and the quantity of it which can accumulate is not proportional to
the quantity of matter but to the extent of surface. But whatever be
the cause, the adhesion is strong, and seemingly cannot be overcome.
If we were to suppose an atom of any body, of oxygen for example, to
remain uncombined with any other body, but surrounded by electricity,
it is obvious that the coating of negative electricity on its surface
would be gradually neutralized by its attracting and combining with
positive electricity. But let us suppose an atom of oxygen and an atom
of hydrogen to be united together, it is obvious that the positive
electricity of the one atom would powerfully attract the negative
electricity of the other, and _vice versâ_. And if these respective
electricities cannot leave the atoms, the two atoms will remain firmly
united, and the opposite electrical intensities will in some measure
neutralize each other, and thus prevent them from being neutralized
by electricity from any other quarter. But a current of the opposite
electricities passing through such a compound, might neutralize the
electricity in each, and thus putting an end to their attractions,
occasion decomposition.
Such is a very imperfect outline of the electrical theory of affinity
first proposed by Davy to account for the decompositions produced by
electricity. It has been universally adopted by chemists; and some
progress has been made in explaining and accounting for the different
phenomena. It would be improper, in a work of this kind, to enter
further into the subject. Those who are interested in such discussions
will find a good deal of information in the first volume of Berzelius's
Treatise on Chemistry, in the introduction to the Traité de Chimie
appliqué aux Arts, by Dumas, or in the introduction to my System of
Chemistry, at present in the press.
Public-domain text, read in full here on John Shaqi.
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