The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Davy having thus got possession of an engine, by means of which the
compounds, whose constituents adhered to each other might be separated,
immediately applied it to the decomposition of potash and soda;
bodies which were admitted to be compounds, though all attempts to
analyze them had hitherto failed. His attempt was successful. When
a platinum wire from the negative pole of a strong battery in full
action was applied to a lump of potash, slightly moistened, and lying
on a platinum tray attached to the positive pole of the battery, small
globules of a white metal soon appeared at its extremity. This white
metal he speedily proved to be the basis of potash. He gave it the name
of _potassium_, and very soon proved, that potash is a compound of five
parts by weight of this metal and one part of oxygen. Potash, then,
is a metallic oxide. He proved soon after that soda is a compound of
oxygen and another white metal, to which he gave the name of _sodium_.
Lime is a compound of _calcium_ and oxygen, magnesia of _magnesium_ and
oxygen, barytes of _barium_ and oxygen, and strontian of _strontium_
and oxygen. In short, the fixed alkalies and alkaline earths, are
metallic oxides. When _lithia_ was afterwards discovered by Arfvedson,
Davy succeeded in decomposing it also by the galvanic battery, and
resolving it into oxygen and a white metal, to which the name of
_lithium_ was given.
Davy did not succeed so well in decomposing alumina, glucina, yttria,
and zirconia, by the galvanic battery: they were not sufficiently good
conductors of electricity; but nobody entertained any doubt that they
also were metallic oxides. They have been all at length decomposed, and
their bases obtained by the joint action of chlorine and potassium,
and it has been demonstrated, that they also are metallic oxides. Thus
it has been ascertained, in consequence of Davy's original discovery
of the powers of the galvanic battery, that all the bases formerly
distinguished into the four classes of alkalies, alkaline earths,
earths proper, and metallic oxides, belong in fact only to one class,
and are all metallic oxides.
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