The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
The very curious and important facts respecting chlorine and muriatic
acid gas which they had ascertained, were made known by Gay-Lussac
and Thenard to the Institute, on the 27th of February, 1809, and an
abstract of them was published in the second volume of the Mémoires
d'Arcueil. There can be little doubt that it was in consequence of
these curious and important experiments of the French chemists that
Davy's attention was again turned to muriatic acid gas. He had already,
in 1808, shown that when potassium is heated in muriatic acid gas,
muriate of potash is formed, and a quantity of hydrogen gas evolved,
amounting to more than one-third of the muriatic acid gas employed,
and he had shown, that in no case can muriatic acid be obtained from
chlorine, unless water or its elements be present. This last conclusion
had been amply confirmed by the new investigations of Gay-Lussac and
Thenard. In 1810 Davy again resumed the examination of the subject, and
in July of that year read a paper to the Royal Society, to prove that
_chlorine_ is a simple substance, and that muriatic acid is a compound
of _chlorine_ and _hydrogen_.
This was introducing an alteration in chemical theory of the same
kind, and nearly as important, as was introduced by Lavoisier, with
respect to the action of oxygen in the processes of combustion and
calcination. It had been previously supposed that sulphur, phosphorus,
charcoal, and metals, were compounds; one of the constituents of which
was phlogiston, and the other the acids or oxides which remained after
the combustion or calcination had taken place. Lavoisier showed that
the sulphur, phosphorus, charcoal, and metals, were simple substances;
and that the acids or calces formed were compounds of these simple
bodies and oxygen. In like manner, Davy showed that chlorine, instead
of being a compound of muriatic acid and oxygen, was, in fact, a simple
substance, and muriatic acid a compound of chlorine and hydrogen.
This new doctrine immediately overturned the Lavoisierian hypothesis
respecting oxygen as the acidifying principle, and altered all the
previously received notions respecting the muriates. What had been
called _muriates_ were, in fact, combinations of chlorine with the
combustible or metal, and were analogous to oxides. Thus, when muriatic
acid gas was made to act upon hot litharge, a double decomposition
took place, the chlorine united to the lead, while the hydrogen of the
muriatic acid united with the oxygen of the litharge, and formed water.
Hence the reason of the appearance of water in this case; and hence it
was obvious that what had been called muriate of lead, was, in reality,
a compound of chlorine and metallic lead. It ought, therefore, to be
called, not muriate of lead, but chloride of lead.
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