The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Important as these discoveries are, and sufficient as they would
have been to immortalize the author of them, they are not the only
ones for which we are indebted to Sir Humphry Davy. His experiments
on _chlorine_ are not less interesting or less important in their
consequences. I have already mentioned in a former chapter, that
Berthollet made a set of experiments on chlorine, from which he had
drawn as a conclusion, that it is a compound of oxygen and muriatic
acid, in consequence of which it got the name of _oxymuriatic acid_.
This opinion of Berthollet had been universally adopted by chemists,
and admitted by them as a fundamental principle, till Gay-Lussac
and Thenard endeavoured, unsuccessfully, to decompose this gas, or
to resolve it into muriatic acid and chlorine. They showed, in the
clearest manner, that such a resolution was impossible, and that no
direct evidence could be adduced to prove that oxygen was one of its
constituents. The conclusion to which they came was, that muriatic acid
gas contained water as an essential constituent; and they succeeded by
this hypothesis in accounting for all the different phenomena which
they had observed. They even made an experiment to determine the
quantity of water thus combined. They passed muriatic acid through hot
litharge (protoxide of lead); muriate of lead was formed, and abundance
of water made its appearance and was collected. They did not attempt to
determine the proportions; but we can now easily calculate the quantity
of water which would be deposited when a given weight of muriatic acid
gas is absorbed by a given weight of litharge. Suppose we have fourteen
parts of oxide of lead: to convert it into muriate of lead, 4·625
parts (by weight) of muriatic acid would be necessary, and during the
formation of the muriate of lead there would be deposited 1·125 parts
of water. So that from this experiment it might be concluded, that
about one-fourth of the weight of muriatic acid gas is water.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account