The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
The next division of the work relates to potassium. Davy had hitherto
produced that metal only in minute quantities by the action of the
galvanic battery upon potash. But Gay-Lussac and Thenard contrived
a process by which it can be prepared on a large scale by chemical
decomposition. Their method was, to put into a bent gun-barrel, well
coated externally with clay, and passed through a furnace, a quantity
of clean iron-filings. To one extremity of this barrel was fitted a
tube containing a quantity of caustic potash. This tube was either shut
at one end by a stopper, or by a glass tube luted to it, and plunged
under the surface of mercury. To the other extremity of the gun-barrel
was also luted a tube, which plunged into a vessel containing mercury.
Heat was applied to the gun-barrel till it was heated to whiteness;
then, by means of a choffer, the caustic potash was melted and made to
trickle slowly into the white-hot iron-filings. At this temperature the
potash undergoes decomposition, the iron uniting with its oxygen. The
potassium is disengaged, and being volatile is deposited at a distance
from the hot part of the tube, where it is collected after the process
is finished.
Being thus in possession, both of potassium and sodium in considerable
quantities, they were enabled to examine its properties more in detail
than Davy had done: but such was the care and industry with which
Davy's experiments had been made that very little remained to be
done. The specific gravity of the two metals was determined with more
precision than it was possible for Davy to do. They determined the
action of these metals on water, and measured the quantity of hydrogen
gas given out with more precision than Davy could. They discovered
also, by heating these metals in oxygen gas, that they were capable of
uniting with an additional dose of oxygen, and of forming peroxides of
potassium and sodium. These oxides have a yellow colour, and give out
the surplus oxygen, and are brought back to the state of potash and
soda when they are plunged into water. They exposed a great variety of
substances to the action of potassium, and brought to light a vast
number of curious and important facts, tending to throw new light on
the properties and characters of that curious metallic substance.
By heating together anhydrous boracic acid and potassium in a copper
tube, they succeeded in decomposing the acid, and in showing it to
be a compound of oxygen, and a black matter like charcoal, to which
the name of _boron_ has been given. They examined the properties of
boron in detail, but did not succeed in determining with exactness
the proportions of the constituents of boracic acid. The subsequent
experiments of Davy, though not exact, come a good deal nearer the
truth.
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