The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Their experiments on fluoric acid are exceedingly valuable. They
first obtained that acid in a state of purity, and ascertained its
properties. Their attempts to decompose it as well as those of Davy,
ended in disappointment. But Ampere conceived the idea that this
acid, like muriatic acid, is a compound of hydrogen with an unknown
supporter of combustion, to which the name _fluorine_ was given.
This opinion was adopted by Davy, and his experiments, though they
do not absolutely prove the truth of the opinion, give it at least
considerable probability, and have disposed chemists in general to
adopt it. The subsequent researches of Berzelius, while they have added
a great deal to our former knowledge respecting fluoric acid and its
compounds, have all tended to confirm and establish the doctrine that
it is a hydracid, and similar in its nature to the other hydracids. But
such is the tendency of fluorine to combine with every substance, that
hitherto it has been impossible to obtain it in an insulated state. We
want therefore, still, a decisive proof of the accuracy of the opinion.
To the experiments of Gay-Lussac and Thenard on chlorine and muriatic
acid, I have already alluded in a former part of this chapter. It was
during their investigations connected with this subject, that they
discovered _fluoboric_ acid gas, which certainly adds considerably
to the probability of the theory of Ampere respecting the nature of
fluoric acid.
I pass over a vast number of other new and important facts and
observations contained in this admirable work, which ought to be
studied with minute attention by every person who aspires at becoming a
chemist.
Besides the numerous discoveries contained in the Recherches
Physico-chimique, Gay-Lussac is the author of two of so much importance
that it would be wrong to omit them. He showed that cyanogen is one
of the constituents of prussic acid; succeeded in determining the
composition of cyanogen, and showing it to be a compound of two
atoms of carbon and one atom of azote. Prussic acid is a compound of
one atom of hydrogen and one atom of cyanogen. Sulpho-cyanic acid,
discovered by Mr. Porrett, is a compound of one atom sulphuric, and
one atom cyanogen; chloro-cyanic acid, discovered by Berthollet, is
a compound of one atom chlorine and one atom cyanogen; while cyanic
acid, discovered by Wöhler, is a compound of one atom oxygen and
one atom cyanogen. I take no notice of the fulminic acid; because,
although Gay-Lussac's experiments are exceedingly ingenious, and his
reasoning very plausible, it is not quite convincing; especially as the
results obtained by Mr. Edmund Davy, and detailed by him in his late
interesting memoir on this subject, are somewhat different.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account