The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Evaporation; and on the Expansion of Gases by Heat."
From a careful examination of all the circumstances, he considered
himself as entitled to infer, that when two elastic fluids or gases,
A and B, are mixed together, there is no mutual repulsion among their
particles; that is, the particles of A do not repel those of B, as they
do one another. Consequently, the pressure or whole weight upon any
one particle arises solely from those of its own kind. This doctrine
is of so startling a nature and so contrary to the opinions previously
received, that chemists have not been much disposed to admit it. But at
the same time it must be confessed, that no one has hitherto been able
completely to refute it. The consequences of admitting it are obvious:
we should be able to account for a fact which has been long known,
though no very satisfactory reason for it had been assigned; namely,
that if two gases be placed in two separate vessels, communicating
by a narrow orifice, and left at perfect rest in a place where the
temperature never varies, if we examine them after a certain interval
of time we shall find both equally diffused through both vessels. If we
fill a glass phial with hydrogen gas and another phial with common air
or carbonic acid gas and unite the two phials by a narrow glass tube
two feet long, filled with common air, and place the phial containing
the hydrogen gas uppermost, and the other perpendicularly below it, the
hydrogen, though lightest, will not remain in the upper phial, nor the
carbonic acid, though heaviest, in the undermost phial; but we shall
find both gases equally diffused through both phials.
Public-domain text, read in full here on John Shaqi.
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