The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
But the second of these essays is by far the most important. In it he
establishes, by the most unexceptionable evidence, that water, when
it evaporates, is always converted into an elastic fluid, similar in
its properties to air. But that the distance between the particles is
greater the lower the temperature is at which the water evaporates.
The elasticity of this vapour increases as the temperature increases.
At 32° it is capable of balancing a column of mercury about half an
inch in height, and at 212° it balances a column thirty inches high,
or it is then equal to the pressure of the atmosphere. He determined
the elasticity of vapour at all temperatures from 32° to 212°, pointed
out the method of determining the quantity of vapour that at any time
exists in the atmosphere, the effect which it has upon the volume of
air, and the mode of determining its quantity. Finally, he determined,
experimentally, the rate of evaporation from the surface of water at
all temperatures from 32° to 212°. These investigations have been of
infinite use to chemists in all their investigations respecting the
specific gravity of gases, and have enabled them to resolve various
interesting problems, both respecting specific gravity, evaporation,
rain and respiration, which, had it not been for the principles laid
down in this essay, would have eluded their grasp.
In the last essay contained in this paper he has shown that all elastic
fluids expand the same quantity by the same addition of heat, and this
expansion is very nearly 1-480th part for every degree of Fahrenheit's
thermometer. In this last branch of the subject Mr. Dalton was followed
by Gay-Lussac, who, about half a year after the appearance of his
Essays, published a paper in the Annales de Chimie, showing that the
expansion of all elastic fluids, when equally heated, is the same. Mr.
Dalton concluded that the expansion of all elastic fluids by heat is
equable. And this opinion has been since confirmed by the important
experiments of Dulong and Petit, which have thrown much additional
light on the subject.
In the year 1804, on the 26th of August, I spent a day or two at
Manchester, and was much with Mr. Dalton. At that time he explained to
me his notions respecting the composition of bodies. I wrote down at
the time the opinions which he offered, and the following account is
taken literally from my journal of that date:
The ultimate particles of all simple bodies are _atoms_ incapable
of further division. These atoms (at least viewed along with their
atmospheres of heat) are all spheres, and are each of them possessed of
particular weights, which may be denoted by numbers. For the greater
clearness he represented the atoms of the simple bodies by symbols. The
following are his symbols for four simple bodies, together with the
numbers attached to them by him in 1804:
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