The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
It was this happy idea of representing the atoms and constitution of
bodies by symbols that gave Mr. Dalton's opinions so much clearness.
I was delighted with the new light which immediately struck my
mind, and saw at a glance the immense importance of such a theory,
when fully developed. Mr. Dalton informed me that the atomic theory
first occurred to him during his investigations of olefiant gas and
carburetted hydrogen gases, at that time imperfectly understood, and
the constitution of which was first fully developed by Mr. Dalton
himself. It was obvious from the experiments which he made upon them,
that the constituents of both were carbon and hydrogen, and nothing
else. He found further, that if we reckon the carbon in each the same,
then carburetted hydrogen gas contains exactly twice as much hydrogen
as olefiant gas does. This determined him to state the ratios of these
constituents in numbers, and to consider the olefiant gas as a compound
of one atom of carbon and one atom of hydrogen; and carburetted
hydrogen of one atom of carbon and two atoms of hydrogen. The idea
thus conceived was applied to carbonic oxide, water ammonia, &c.; and
numbers representing the atomic weights of oxygen, azote, &c., deduced
from the best analytical experiments which chemistry then possessed.
Let not the reader suppose that this was an easy task. Chemistry at
that time did not possess a single analysis which could be considered
as even approaching to accuracy. A vast number of facts had been
ascertained, and a fine foundation laid for future investigation; but
nothing, as far as weight and measure were concerned, deserving the
least confidence, existed. We need not be surprised, then, that Mr.
Dalton's first numbers were not exact. It required infinite sagacity,
and not a little labour, to come so near the truth as he did. How could
accurate analyses of gases be made when there was not a single gas
whose specific gravity was known, with even an approach to accuracy;
the preceding investigations of Dalton himself paved the way for
accuracy in this indispensable department; but still accurate results
had not yet been obtained.
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