The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
In the third edition of my System of Chemistry, published in 1807, I
introduced a short sketch of Mr. Dalton's theory, and thus made it
known to the chemical world. The same year a paper of mine on _oxalic
acid_ was published in the Philosophical Transactions, in which I
showed that oxalic acid unites in two proportions with strontian,
forming an _oxalate_ and _binoxalate_; and that, supposing the
strontian in both salts to be the same, the oxalic acid in the latter
is exactly twice as much as in the former. About the same time, Dr.
Wollaston showed that bicarbonate of potash contains just twice the
quantity of carbonic acid that exists in carbonate of potash; and that
there are three oxalates of potash; viz., _oxalate_, _binoxalate_, and
_quadroxalate_; the weight of acids in each of which are as the numbers
1, 2, 4. These facts gradually drew the attention of chemists to Mr.
Dalton's views. There were, however, some of our most eminent chemists
who were very hostile to the atomic theory. The most conspicuous
of these was Sir Humphry Davy. In the autumn of 1807 I had a long
conversation with him at the Royal Institution, but could not convince
him that there was any truth in the hypothesis. A few days after I
dined with him at the Royal Society Club, at the Crown and Anchor,
in the Strand. Dr. Wollaston was present at the dinner. After dinner
every member of the club left the tavern, except Dr. Wollaston, Mr.
Davy, and myself, who staid behind and had tea. We sat about an hour
and a half together, and our whole conversation was about the atomic
theory. Dr. Wollaston was a convert as well as myself; and we tried to
convince Davy of the inaccuracy of his opinions; but, so far from being
convinced, he went away, if possible, more prejudiced against it than
ever. Soon after, Davy met Mr. Davis Gilbert, the late distinguished
president of the Royal Society; and he amused him with a caricature
description of the atomic theory, which he exhibited in so ridiculous a
light, that Mr. Gilbert was astonished how any man of sense or science
could be taken in with such a tissue of absurdities. Mr. Gilbert
called on Dr. Wollaston (probably to discover what could have induced
a man of Dr. Wollaston's sagacity and caution to adopt such opinions),
and was not sparing in laying the absurdities of the theory, such as
they had been represented to him by Davy, in the broadest point of
view. Dr. Wollaston begged Mr. Gilbert to sit down, and listen to
a few facts which he would state to him. He then went over all the
principal facts at that time known respecting the salts; mentioned the
alkaline carbonates and bicarbonates, the oxalate, binoxalate, and
quadroxalate of potash, carbonic oxide and carbonic acid, olefiant gas,
and carburetted hydrogen; and doubtless many other similar compounds,
in which the proportion of one of the constituents increases in a
regular ratio. Mr. Gilbert went away a convert to the truth of the
Public-domain text, read in full here on John Shaqi.
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