The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
He had made choice of hydrogen for unity, because it is the lightest
of all bodies. He was of opinion that the atomic weights of all other
bodies are multiples of hydrogen; and, accordingly, they are all
expressed in whole numbers. He had raised the atomic weight of oxygen
from 6·5 to 7, from a more careful examination of the experiments
on the component parts of water. Davy, from a more accurate set of
experiments, soon after raised the number for oxygen to 7·5: and
Dr. Prout, from a still more careful investigation of the relative
specific gravities of oxygen and hydrogen, showed that if the atom of
hydrogen be 1, that of oxygen must be 8. Every thing conspires to prove
that this is the true ratio between the atomic weights of oxygen and
hydrogen.
In 1810 appeared the second volume of Mr. Dalton's New System of
Chemical Philosophy. In it he examines the elementary principles,
or simple bodies, namely, oxygen, hydrogen, azote, carbon, sulphur,
phosphorus, and the metals; and the compounds consisting of two
elements, namely, the compounds of oxygen with hydrogen, azote,
carbon, sulphur, phosphorus; of hydrogen with azote, carbon, sulphur,
phosphorus. Finally he treats of the fixed alkalies and earths. All
these combinations are treated of with infinite sagacity; and he
endeavours to determine the atomic weights of the different elementary
substances. Nothing can exceed the ingenuity of his reasoning. But
unfortunately at that time very few accurate chemical analyses existed;
and in chemistry no reasoning, however ingenious, can compensate for
this indispensable datum. Accordingly his table of atomic weights at
the end this second volume, though much more complete than that at the
end of the first volume, is still exceedingly defective; indeed no one
number can be considered as perfectly correct.
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