The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
The third volume of the New System of Chemical Philosophy was only
published in 1827; but the greatest part of it had been printed nearly
ten years before. It treats of the metallic oxides, the sulphurets,
phosphurets, carburets, and alloys. Doubtless many of the facts
contained in it were new when the sheets were put to the press; but
during the interval between the printing and publication, almost the
whole of them had not merely been anticipated, but the subject carried
much further. By far the most important part of the volume is the
Appendix, consisting of about ninety pages, in which he discusses,
with his usual sagacity, various important points connected with heat
and vapour. In page 352 he gives a new table of the atomic weights of
bodies, much more copious than those contained in the two preceding
volumes; and into which he has introduced the corrections necessary
from the numerous correct analyses which had been made in the interval.
He still adheres to the ratio 1:7 as the correct difference between the
weights of the atoms of hydrogen and oxygen. This shows very clearly
that he has not attended to the new facts which have been brought
forward on the subject. No person who has attended to the experiments
made on the specific gravity of these two gases during the last twelve
years, could admit that these specific gravities are to each other as 1
to 14. If 1 to 16 be not the exact ratio, it will surely be admitted on
all hands that it is infinitely near it.
Mr. Dalton represented the weight of an atom of hydrogen by 1, because
it is the lightest of bodies. In this he has been followed by the
chemists of the Royal Institution, by Mr. Philips, Dr. Henry, and
Dr. Turner, and perhaps some others whose names I do not at present
recollect. Dr. Wollaston, in his paper on Chemical Equivalents,
represented the atomic weight of oxygen by 1, because it enters into
a greater number of combinations than any other substance; and this
plan has been adopted by Berzelius, by myself, and by the greater
number, if not the whole, of the chemists on the continent. Perhaps the
advantage which Dr. Wollaston assigned for making the atom of oxygen
unity will ultimately disappear: for there is no reason for believing
that the other supporters of combustion are not capable of entering
into as many compounds as oxygen. But, from the constitution of the
atmosphere, it is obvious that the compounds into which oxygen enters
will always be of more importance to us than any others; and in this
point of view it may be attended with considerable convenience to have
oxygen represented by 1. In the present state of the atomic theory
there is another reason for making the atom of oxygen unity, which I
think of considerable importance. Chemists are not yet agreed about the
atom of hydrogen. Some consider water a compound of 1 atom of oxygen
and 2 atoms of hydrogen; others, of 1 atom of oxygen and 1 atom of
hydrogen.
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