The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
According to the first view, the atom of hydrogen is only
1-16th of the weight of an atom of oxygen; according to the second, it
is 1-8th. If, therefore, we were to represent the atom of hydrogen by
1, the consequence would be, that two tables of atomic weights would be
requisite--all the atoms in one being double the weight of the atoms in
the other: whereas, if we make the atom of oxygen unity, it will be the
atom of hydrogen only that will differ in the two tables. In the one
table it will be 0·125, in the other it will be 0·0625: or, reckoning
with Berzelius the atom of oxygen = 100, we have that of hydrogen =
12·5 or 6·25, according as we view water to be a compound of 1 atom of
oxygen with 1 or 2 atoms of hydrogen.
In the year 1809 Gay-Lussac published in the second volume of the
Mémoires d'Arcueil a paper on the union of the gaseous substances with
each other. In this paper he shows that the proportions in which the
gases unite with each other are of the simplest kind. One volume of one
gas either combining with one volume of another, or with two volumes,
or with half a volume. The atomic theory of Dalton had been opposed
with considerable keenness by Berthollet in his Introduction to the
French translation of my System of Chemistry. Nor was this opposition
to be wondered at; because its admission would of course overturn all
the opinions which Berthollet had laboured to establish in his Chemical
Statics. The object of Gay-Lussac's paper was to confirm and establish
the new atomic theory, by exhibiting it in a new point of view. Nothing
can be more ingenious than his mode of treating the subject, or more
complete than the proofs which he brings forward in support of it. It
had been already established that water is formed by the union of one
volume of oxygen and two volumes of hydrogen gas. Gay-Lussac found by
experiment, that one volume of muriatic acid gas is just saturated by
one volume of ammoniacal gas: the product is sal ammoniac. Fluoboric
acid gas unites in two proportions with ammoniacal gas: the first
compound consists of one volume of fluoboric gas, and one volume of
ammoniacal; the second, of one volume of the acid gas, and two volumes
of the alkaline. The first forms a neutral salt, the second an alkaline
salt. He showed likewise, that carbonic acid and ammoniacal gas could
combine also in two proportions; namely, one volume of the acid gas
with one or two volumes of the alkaline gas.
M. Amédée Berthollet had proved that ammonia is a compound of one
volume of azotic, and three volumes of hydrogen gas. Gay-Lussac himself
had shown that sulphuric acid is composed of one volume sulphurous
acid gas, and a half-volume of oxygen gas. He showed further, that the
compounds of azote and oxygen were composed as follows:
Azote. Oxygen.
Protoxide of azote 1 volume + ½ volume
Deutoxide of azote 1 " + 1
Nitrous acid 1 " + 2
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