The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Atomic weight. Sp. gravity.
Ammoniacal gas 2·125 0·5902[.7]
Hydrocyanic acid 3·375 0·9375
Deutoxide of azote 3·75 1·041[.6]
Muriatic acid 4·625 1·2847[.2]
Hydrobromic acid 10·125 2·8125
Hydriodic acid 15·875 4·40973
[Transcriber's Note: The numbers within [] thus [.2] represent numbers
with a dot above them in the original.]
When Professor Berzelius, of Stockholm, thought of writing his
Elementary Treatise on Chemistry, the first volume of which was
published in the year 1808, he prepared himself for the task by reading
several chemical works which do not commonly fall under the eye of
those who compose elementary treatises. Among other books he read the
Stochiometry of Richter, and was much struck with the explanations
there given of the composition of salts, and the precipitation of
metals by each other. It followed from the researches of Richter, that
if we were in possession of good analyses of certain salts, we might
by means of them calculate with accuracy the composition of all the
rest. Berzelius formed immediately the project of analyzing a series
of salts with the most minute attention to accuracy. While employed in
putting this project in execution, Davy discovered the constituents
of the alkalies and earths, Mr. Dalton gave to the world his notions
respecting the atomic theory, and Gay-Lussac made known his theory of
volumes. This greatly enlarged his views as he proceeded, and induced
him to embrace a much wider field than he had originally contemplated.
His first analyses were unsatisfactory; but by repeating them and
varying the methods, he detected errors, improved his processes, and
finally obtained results, which agreed exceedingly well with the
theoretical calculations. These laborious investigations occupied him
several years. The first outline of his experiments appeared in the
77th volume of the Annales de Chimie, in 1811, in a letter addressed
by Berzelius to Berthollet. In this letter he gives an account of
his methods of analyses together with the composition of forty-seven
compound bodies. He shows that when a metallic protosulphuret is
converted into a sulphate, the sulphate is neutral; that an atom of
sulphur is twice as heavy as an atom of oxygen; and that when sulphite
of barytes is converted into sulphate, the sulphate is neutral, there
being no excess either of acid or base. From these and many other
important facts he finally draws this conclusion: "In a compound formed
by the union of two oxides, the one which (when decomposed by the
galvanic battery) attaches itself to the positive pole (the _acid_ for
example) contains two, three, four, five, &c., times as much oxygen,
as the one which attaches itself to the negative pole (the alkali,
earth, or metallic oxide)." Berzelius's essay itself appeared in the
third volume of the Afhandlingar, in 1810. It was almost immediately
Public-domain text, read in full here on John Shaqi.
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