The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
translated into German, and published by Gilbert in his Annalen der
Physik. But no English translation has ever appeared, the editors of
our periodical works being in general unacquainted with the German
and other northern languages. In 1815 Berzelius applied the atomic
theory to the mineral kingdom, and showed with infinite ingenuity that
minerals are chemical compounds in definite or atomic proportions, and
by far the greater number of them combinations of acids and bases. He
applied the theory also to the vegetable kingdom by analyzing several
of the vegetable acids, and showing their atomic constitution. But
here a difficulty occurs, which in the present state of our knowledge,
we are unable to surmount. There are two acids, the _acetic_ and
_succinic_, that are composed of exactly the same number, and same kind
of atoms, and whose atomic weight is 6·25. The constituents of these
two acids are
Atomic weight.
2 atoms hydrogen 0·25
4 " carbon 3
3 " oxygen 3
----
6·25
So that they consist of _nine_ atoms. Now as these two acids are
composed of the same number and the same kind of atoms, one would
expect that their properties should be the same; but this is not the
case: acetic acid has a strong and aromatic smell, succinic acid has
no smell whatever. Acetic acid is so soluble in water that it is
difficult to obtain it in crystals, and it cannot be procured in a
separate state free from water; for the crystals of acetic acid are
composed of one atom of acid and one atom of water united together; but
succinic acid is not only easily obtained free from water, but it is
not even very soluble in that liquid. The nature of the salts formed
by these two acids is quite different; the action of heat upon each
is quite different; the specific gravity of each differs. In short
all their properties exhibit a striking contrast. Now how are we to
account for this? Undoubtedly by the different ways in which the atoms
are arranged in each. If the electro-chemical theory of combination be
correct, we can only view atoms as combining two by two. A substance
then, containing nine atoms, such as acetic acid, must be of a very
complex nature. And it is obvious enough that these nine atoms might
arrange themselves in a great variety of binary compounds, and the way
in which these binary compounds unite may, and doubtless does, produce
a considerable effect upon the nature of the compound formed. Thus, if
we make use of Mr. Dalton's symbols to represent the atoms of hydrogen,
carbon and oxygen, we may suppose the nine atoms constituting acetic
and succinic acid to be arranged thus:
[hydrogen][carbon][hydrogen]
[oxygen][oxygen][oxygen]
[carbon][carbon][carbon]
Or thus:
[carbon][hydrogen][carbon]
[oxygen][oxygen][oxygen]
[carbon][hydrogen][carbon]
Now, undoubtedly these two arrangements would produce a great change in
the nature of the compound.
Public-domain text, read in full here on John Shaqi.
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