The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Perhaps the reader will excuse me if to the preceding historical
details I add a few words to make him acquainted with my own attempts
to render the atomic theory more accurate by new and careful analyses.
I shall not say any thing respecting the experiments which I undertook
to determine the specific gravity of the gases; though they were
performed with much care, and at a considerable expense, and though
I believe the results obtained approached accuracy as nearly as the
present state of chemical apparatus enables us to go. In the year
1819 I began a set of experiments to determine the exact composition
of the salts containing the different elementary bodies by means of
double decomposition, as was done by Wenzel, conceiving that in that
way the results would be very near the truth, while the experiments
would be more easily made. My mode was to dissolve, for example, a
certain weight of muriate of barytes in distilled water, and then to
ascertain by repeated trials what weight of sulphate of soda must be
added to precipitate the whole of the barytes without leaving any
surplus of sulphuric acid in the liquid. To determine this I put
into a watch-glass a few drops of the filtered liquor consisting of
the mixture of solutions of the two salts: to this I added a drop of
solution of sulphate of soda. If the liquid remained clear it was a
proof that it contained no sensible quantity of barytes. To another
portion of the liquid, also in a watch-glass, I added a drop of muriate
of barytes. If there was no precipitate it was a proof that the liquid
contained no sensible quantity of sulphuric acid. If there was a
precipitate, on the addition of either of these solutions, it showed
that there was an excess of one or other of the salts. I then mixed
the two salts in another proportion, and proceeded in this way till I
had found two quantities which when mixed exhibited no evidence of the
residual liquid containing any sulphuric acid or barytes. I considered
these two weights of the salts as the equivalent weights of the salt,
or as weights proportional to an integrant particle of each salt. I
made no attempt to collect the two new formed salts and to weigh them
separately.
I published the result of my numerous experiments in 1825, in a work
entitled "An Attempt to establish the First Principles of Chemistry by
Experiment." The most valuable part of this book is the account of the
salts; about three hundred of which I subjected to actual analysis. Of
these the worst executed are the phosphates; for with respect to them
I was sometimes misled by my method of double decomposition. I was not
aware at first, that, in certain cases, the proportion of acid in
these salts varies, and the phosphate of soda which I employed gave me
a wrong number for the atomic weight of phosphoric acid.
CHAPTER VII.
OF THE PRESENT STATE OF CHEMISTRY.
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