The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
There is something in the vegetable acids quite different from the
acids of the inorganic kingdom, and which would lead to the suspicion
that the electro-chemical theory will not apply to them as it does to
the others. In the acids of carbon, sulphur, phosphorus, selenium, &c.,
we find one atom of a positive substance united to one, two, or three
of a negative substance: we are not surprised, therefore, to find the
acid formed negative also. But in acetic and succinic acids we find
every atom of oxygen united with two electro-positive atoms: the wonder
then is, that the acid should not only retain its electro-negative
properties, but that it should possess considerable power as an acid.
In benzoic acid, for every atom of oxygen, there are present no fewer
than seven electro-positive atoms.
Berzelius has returned to these analytical experiments repeatedly, so
that at last he has brought his results very near the truth indeed.
It is to his labours chiefly that the great progress which the atomic
theory has made is owing.
In the year 1814 there appeared in the Philosophical Transactions a
description of a Synoptical Scale of Chemical Equivalents, by Dr.
Wollaston. In this paper we have the equivalents or atomic weights
of seventy-three different bodies, deduced chiefly from a sagacious
comparison of the previous analytical experiments of others, and almost
all of them very near the truth. These numbers are laid down upon
a sliding rule, by means of a table of logarithms, and over against
them the names of the substances. By means of this rule a great many
important questions respecting the substances contained on the scale
may be solved. Hence the scale is of great advantage to the practical
chemist. It gives, by bare inspection, the constituents of all the
salts contained on it, the quantity of any other ingredient necessary
to decompose any salt, and the weights of the new constituents that
will be formed. The contrivance of this scale, therefore, may be
considered as an important addition to the atomic theory. It rendered
that theory every where familiar to all those who employed it. To
it chiefly we owe, I believe, the currency of that theory in Great
Britain; and the prevalence of the mode which Dr. Wollaston introduced,
namely, of representing the atom of oxygen by unity, or at least by
ten, which comes nearly to the same thing.
Public-domain text, read in full here on John Shaqi.
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