The History of Chemistry, Volume 2 (of 2) — John Shaqi
The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
19. The last of the labours of Bergman which I shall notice here is
his Essay on Elective Attractions, which was originally published
in 1775, but was much augmented and improved in the third volume of
his Opuscula, published in 1783. An English translation of this last
edition of the Essay was made by Dr. Beddoes, and was long familiar to
the British chemical world. The object of this essay was to elucidate
and explain the nature of chemical affinity, and to account for all the
apparent anomalies that had been observed. He laid it down as a first
principle, that all bodies capable of combining chemically with each
other, have an attraction for each other, and that this attraction is
a definite and fixed force which may be represented by a number. Now
the bodies which have the property of uniting together are chiefly the
acids and the alkalies, or bases. Every acid has an attraction for each
of the alkalies or bases; but the force of this attraction differs in
each. Some bases have a strong attraction for acids, and others a weak;
but the attractive force of each may be expressed by numbers.
Now, suppose that an acid _a_ is united with a base _m_ with a certain
force, if we mix the compound _a m_ with a certain quantity of the
base _n_, which has a stronger attraction for _a_ than _m_ has, the
consequence will be, that _a_ will leave _m_ and unite with _n_;--_n_
having a stronger attraction for _a_ than _m_ has, will disengage it
and take its place. In consequence of this property, which Bergman
considered as the foundation of the whole of the science, the
strength of affinity of one body for another is determined by these
decompositions and combinations. If _n_ has a stronger affinity for
_a_ than _m_ has, then if we mix together _a_, _m_, and _n_ in the
requisite proportions, _a_ and _n_ will unite together, leaving _m_
uncombined: or if we mix _n_ with the compound _a m_, _m_ will be
disengaged. Tables, therefore, may be drawn up, exhibiting the strength
of these affinities. At the top of a column is put the name of an
_acid_ or a _base_, and below it are put the names of all the _bases_
or _acids_ in the order of their affinity. The following little table
will exhibit a specimen of these columns:
_Sulphuric Acid._
Barytes
Strontian
Potash
Soda
Lime
Magnesia.
Here sulphuric acid is the substance placed at the head of the column,
and under it are the names of the bases capable of uniting with it in
the order of their affinity. Barytes, which is highest up, has the
strongest affinity, and magnesia, which is lowest down, has the weakest
affinity. If sulphuric acid and magnesia were combined together, all
the bases whose names occur in the table above magnesia would be able
to separate the sulphuric acid from it. Potash would be disengaged from
sulphuric acid by barytes and strontian, but not by soda, lime, and
magnesia.
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