The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
19. In the Memoires de l'Académie, for 1782 (printed in 1785), we
have a paper by Lavoisier on a method of augmenting considerably the
action of fire and of heat. The method which he proposes is a jet of
oxygen gas, striking against red-hot charcoal. He gives the result
of some trials made in this way. Platinum readily melted. Pieces of
ruby or sapphire were softened sufficiently to run together into one
stone. Hyacinth lost its colour, and was also softened. Topaz lost its
colour, and melted into an opaque enamel. Emeralds and garnets lost
their colour, and melted into opaque coloured glasses. Gold and silver
were volatilized; all the other metals, and even the metallic oxides,
were found to burn. Barytes also burns when exposed to this violent
heat. This led Lavoisier to conclude, as Bergman had done before him,
that Barytes is a metallic oxide. This opinion has been fully verified
by modern chemists. Both silica and alumina were melted. But he could
not fuse lime nor magnesia. We are now in possession of a still more
powerful source of heat in the oxygen and hydrogen blowpipe, which is
capable of fusing both lime and magnesia, and, indeed, every substance
which can be raised to the requisite heat without burning or being
volatilized. This subject was prosecuted still further by Lavoisier
in another paper inserted in a subsequent volume of the Memoires de
l'Académie. He describes the effect on rock-crystal, quartz, sandstone,
sand, phosphorescent quartz, milk quartz, agate, chalcedony, cornelian,
flint, prase, nephrite, jasper, felspar, &c.
20. In the same volume is inserted a memoir "On the Nature of the
aeriform elastic Fluids which are disengaged from certain animal
Substances in a state of Fermentation." He found that a quantity of
recent human fæces, amounting to about five cubic inches, when kept
at a temperature approaching to 60° emitted, every day for a month,
about half a cubic inch of gas. This gas was a mixture of eleven parts
carbonic acid gas, and one part of an inflammable gas, which burnt
with a blue flame, and was therefore probably carbonic oxide. Five
cubic inches of old human fæces from a necessary kept in the same
temperature, during the first fifteen days emitted about a third of
a cubic inch of gas each day; and during each of the second fifteen
days, about one fourth of a cubic inch. This gas was a mixture of
thirty-eight volumes of carbonic acid gas, and sixty-two volumes of a
combustible gas, burning with a blue flame, and probably carbonic oxide.
Fresh fæces do not effervesce with dilute sulphuric acid, but old moist
fæces do, and emit about eight times their volume of carbonic acid
gas. Quicklime, or caustic potash, mixed with fæces, puts a stop to
the evolution of gas, doubtless by preventing all fermentation. During
effervescence of fæcal matter the air surrounding it is deprived of a
little of its oxygen, probably in consequence of its combining with the
nascent inflammable gas which is slowly disengaged.
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