The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
II. We come now to the new theory of combustion of which Lavoisier
was the author, and upon which his reputation with posterity will
ultimately depend. Upon this subject, or at least upon matters more
or less intimately connected with it, no fewer than twenty-seven
memoirs of his, many of them of a very elaborate nature, and detailing
expensive and difficult experiments, appeared in the different
volumes of the academy between 1774 and 1788. The analogy between the
combustion of bodies and the calcination of metals had been already
observed by chemists, and all admitted that both processes were
owing to the same cause; namely, the emission of _phlogiston_ by the
burning or calcining body. The opinion adopted by Lavoisier was, that
during burning and calcination nothing whatever left the bodies, but
that they simply united with a portion of the air of the atmosphere.
When he first conceived this opinion he was ignorant of the nature
of atmospheric air, and of the existence of oxygen gas. But after
that principle had been discovered, and shown to be a constituent of
atmospherical air, he soon recognised that it was the union of oxygen
with the burning and calcining body that occasioned the phenomena. Such
is the outline of the Lavoisierian theory stated in the simplest and
fewest words. It will be requisite to make a few observations on the
much-agitated question whether this theory originated with him.
It is now well known that John Rey, a physician at Bugue, in Perigord,
published a book in 1630, in order to explain the cause of the increase
of weight which lead and tin experience during their calcination. After
refuting in succession all the different explanations of this increase
of weight which had been advanced, he adds, "To this question, then,
supported on the grounds already mentioned, I answer, and maintain
with confidence, that the increase of weight arises from the air,
which is condensed, rendered heavy and adhesive by the violent and
long-continued heat of the furnace. This air mixes itself with the calx
(frequent agitation conducing), and attaches itself to the minutest
molecules, in the same manner as water renders heavy sand which is
agitated with it, and moistens and adheres to the smallest grains."
There cannot be the least doubt from this passage that Rey's opinion
was precisely the same as the original one of Lavoisier, and had
Lavoisier done nothing more than merely state in general terms that
during calcination air unites with the calcining bodies, it might have
been suspected that he had borrowed his notions from those of Rey. But
the discovery of oxygen, and the numerous and decisive proofs which
he brought forward that during burning and calcination oxygen unites
with the burning and calcining body, and that this oxygen may be again
separated and exhibited in its original elastic state oblige us to
alter our opinion. And whether we admit that he borrowed his original
Public-domain text, read in full here on John Shaqi.
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