The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
The next set of experiments made by Lavoisier to confirm or extend
his theory, was "On the Combustion of Phosphorus, and the Nature of
the Acid which results from that Combustion." It appeared in the
Memoirs of the Academy, for 1777. The result of these experiments
was very striking. When phosphorus is burnt in a given bulk of air
in sufficient quantity, about four-fifths of the volume of the air
disappears and unites itself with the phosphorus. The residual portion
of the air is incapable of supporting combustion or maintaining animal
life. Lavoisier gave it the name of _mouffette atmospherique_, and he
describes several of its properties. The phosphorus by combining with
the portion of air which has disappeared, is converted into phosphoric
acid, which is deposited on the inside of the receiver in which the
combustion is performed, in the state of fine white flakes. One grain
by this process is converted into two and a half grains of phosphoric
acid. These observations led to the conclusion that atmospheric air
is a mixture or compound of two distinct gases, the one (_oxygen_)
absorbed by burning phosphorus, the other (_azote_) not acted on by
that principle, and not capable of uniting with or calcining metals.
These conclusions had already been drawn by Scheele from similar
experiments, but Lavoisier was ignorant of them.
In the second part of this paper, Lavoisier describes the properties
of phosphoric acid, and gives an account of the salts which it forms
with the different bases. The account of these salts is exceedingly
imperfect, and it is remarkable that Lavoisier makes no distinction
between phosphate of potash and phosphate of soda; though the different
properties of these two salts are not a little striking. But these were
not the investigations in which Lavoisier excelled.
The next paper in which the doctrines of the antiphlogistic theory
were still further developed, was inserted in the Memoirs of the
Academy, for 1777. It is entitled, "On the Combustion of Candles in
atmospherical Air, and in Air eminently Respirable." This paper is
remarkable, because in it he first notices Dr. Priestley's discovery of
oxygen gas; but without any reference to the preceding paper, or any
apology for not having alluded in it to the information which he had
received from Dr. Priestley.
He begins by saying that it is necessary to distinguish four different
kinds of air. 1. Atmospherical air in which we live, and which we
breath. 2. Pure air (_oxygen_), alone fit for breathing, constituting
about the fourth of the volume of atmospherical air, and called by Dr.
Priestley _dephlogisticated air_. 3. Azotic gas, which constitutes
about three-fourths of the volume of atmospherical air, and whose
properties are still unknown. 4. Fixed air, which he proposed to call
(as Bucquet had done) _acide crayeux_, _acid of chalk_.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account