The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
In this paper Lavoisier gives an account of a great many trials that
he made by burning candles in given volumes of atmospherical air and
oxygen gas enclosed in glass receivers, standing over mercury. The
general conclusion which he deduces from these experiments are--that
the azotic gas of the air contributes nothing to the burning of
the candle; but the whole depends upon the oxygen gas of the air,
constituting in his opinion one-fourth of its volume; that during the
combustion of a candle in a given volume of air only two-fifths of
the oxygen are converted into carbonic acid gas, while the remaining
three-fifths remain unaltered; but when the combustion goes on in
oxygen gas a much greater proportion (almost the whole) of this gas
is converted into carbonic acid gas. Finally, that phosphorus, when
burnt in air acts much more powerfully on the oxygen of the air than a
lighted candle, absorbing four-fifths of the oxygen and converting it
into phosphoric acid.
It is evident that at the time this paper was written, Lavoisier's
theory was nearly complete. He considered air as a mixture of three
volumes of azotic gas, and one volume of oxygen gas. The last alone
was concerned in combustion and calcination. During these processes a
portion of the oxygen united with the burning body, and the compound
formed constituted the acid or the calx. Thus he was able to account
for combustion and calcination without having recourse to phlogiston.
It is true that several difficulties still lay in his way, which he
was not yet able to obviate, and which prevented any other person from
adopting his opinions. One of the greatest of these was the fact that
hydrogen gas was evolved during the solution of several metals in
dilute sulphuric or muriatic acid; that by this solution these metals
were converted into calces, and that calces, when heated in hydrogen
gas, were reduced to the metallic state while the hydrogen disappeared.
The simplest explanation of these phenomena was the one adopted by
chemists at the time. Hydrogen was considered as phlogiston. By
dissolving metals in acids, the phlogiston was driven off and the calx
remained: by heating the calx in hydrogen, the phlogiston was again
absorbed and the calx reduced to the metallic state.
Public-domain text, read in full here on John Shaqi.
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