The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
This forms a tolerable approximation to the truth. It is now
known, that the quantity of oxygen in the oxide of iron formed by
the combustion of iron in oxygen gas is not quite uniform in its
composition; sometimes it is a compound of
Iron 3½
Oxygen 1⅓
While at other times it consists very nearly of
Iron 3·5
Oxygen 1
and probably it may exist in all the intermediate proportions between
these two extremes. The last of these compounds constitutes what is
now known by the name of _protoxide_, or _black oxide of iron_. The
first is the composition of the ore of iron so abundant, which is
distinguished by the name of _magnetic iron ore_.
Lavoisier was aware that iron combines with more oxygen than exists
in the protoxide; indeed, his analysis of peroxide of iron forms a
tolerable approximation to the truth; but there is no reason for
believing that he was aware that iron is capable of forming only two
oxides, and that all intermediate degrees of oxidation are impossible.
This was first demonstrated by Proust.
I think it unnecessary to enter into any details respecting two papers
of Lavoisier, that made their appearance in the Memoirs of the Academy,
for 1783, as they add very little to what he had already done. The
first of these describes the experiments which he made to determine the
quantity of oxygen which unites with sulphur and phosphorus when they
are burnt: it contains no fact which he had not stated in his former
papers, unless we are to consider his remark, that the heat given out
during the burning of these bodies has no sensible weight, as new.
The other paper is "On Phlogiston;" it is very elaborate, but contains
nothing which had not been already advanced in his preceding memoirs.
Chemists were so wedded to the phlogistic theory, their prejudices
were so strong, and their understandings so fortified against every
thing that was likely to change their opinions, that Lavoisier found
it necessary to lay the same facts before them again and again, and to
place them in every point of view. In this paper he gives a statement
of his own theory of combustion, which he had previously done in
several preceding papers. He examines the phlogistic theory of Stahl at
great length, and refutes it.
Public-domain text, read in full here on John Shaqi.
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