The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
In the Memoirs of the Academy, for 1784, Lavoisier published a very
elaborate set of experiments on the combustion of alcohol, oil, and
different combustible bodies, which gave a beginning to the analysis
of vegetable substances, and served as a foundation upon which this
most difficult part of chemistry might be reared. He showed that during
the combustion of alcohol the oxygen of the air united to the vapour
of the alcohol, which underwent decomposition, and was converted
into water and carbonic acid. From these experiments he deduced as a
consequence, that the constituents of alcohol are carbon, hydrogen,
and oxygen, and nothing else; and he endeavoured from his experiments
to determine the relative proportions of these different constituents.
From these experiments he concluded, that the alcohol which he used in
his experiments was a compound of
Carbon 2629·5 part.
Hydrogen 725·5
Water 5861
It would serve no purpose to attempt to draw any consequences from
these experiments; as Lavoisier does not mention the specific gravity
of the alcohol, of course we cannot say how much of the water found
was merely united with the alcohol, and how much entered into
its composition. The proportion between the carbon and hydrogen,
constitutes an approximation to the truth, though not a very near one.
Olive oil he showed to be a compound of hydrogen and carbon, and bees'
wax to be a compound of the same constituents, though in a different
proportion.
This subject was continued, and his views further extended, in a
paper inserted in the Memoirs of the Academy, for 1786, entitled,
"Reflections on the Decomposition of Water by Vegetable and Animal
Substances." He begins by stating that when charcoal is exposed to
a strong heat, it gives out a little carbonic acid gas and a little
inflammable air, and after this nothing more can be driven off, however
high the temperature be to which it is exposed; but if the charcoal
be left for some time in contact with the atmosphere it will again
give out a little carbonic acid gas and inflammable gas when heated,
and this process may be repeated till the whole charcoal disappears.
This is owing to the presence of a little moisture which the charcoal
imbibes from the air. The water is decomposed when the charcoal is
heated and converted into carbonic acid and inflammable gas. When
vegetable substances are heated in a retort, the water which they
contain undergoes a similar decomposition, the carbon which forms one
of their constituents combines with the oxygen and produces carbonic
acid, while the hydrogen, the other constituent of the water, flies
off in the state of gas combined with a certain quantity of carbon.
Hence the substances obtained when vegetable or animal substances
are distilled did not exist ready formed in the body operated on;
but proceeded from the double decompositions which took place by the
mutual action of the constituents of the water, sugar, mucus, &c.,
Public-domain text, read in full here on John Shaqi.
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