The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Lavoisier, in the course of his investigations, had proved that
carbonic acid is a compound of carbon and oxygen; sulphuric acid,
of sulphur and oxygen; phosphoric acid, of phosphorus and oxygen;
and nitric acid, of nitrous gas and oxygen. Neither the carbon, the
sulphur, the phosphorus, nor the nitrous gas, possessed any acid
properties when uncombined; but they acquired these properties when
they were united to oxygen. He observed further, that all the acids
known in his time which had been decomposed were found to contain
oxygen, and when they were deprived of oxygen, they lost their acid
properties. These facts led him to conclude, that oxygen is an
essential constituent in all acids, and that it is the principle
which bestows acidity or the true acidifying principle. This was the
reason why he distinguished it by the name of oxygen.[5] These views
were fully developed by Lavoisier, in a paper inserted in the Memoirs
of the Academy, for 1778, entitled, "General Considerations on the
Nature of Acids, and on the Principles of which they are composed."
When this paper was published, Lavoisier's views were exceedingly
plausible. They were gradually adopted by chemists in general, and
for a number of years may be considered to have constituted a part of
the generally-received doctrines. But the discovery of the nature of
chlorine, and the subsequent facts brought to light respecting iodine,
bromine, and cyanogen, have demonstrated that it is inaccurate; that
many powerful acids exist which contain no oxygen, and that there is
no one substance to which the name of acidifying principle can with
justice be given. To this subject we shall again revert, when we come
to treat of the more modern discoveries.
[5] From ὀξυς, sour, and γινομαι, which he defined the _producer of
acids_, the _acidifying principle_.
Long as the account is which we have given of the labours of Lavoisier,
the subject is not yet exhausted. Two other papers of his remain to be
noticed, which throw considerable light on some important functions
of the living body: we allude to his experiments on _respiration_ and
_perspiration_.
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