The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
From these experiments it follows clearly, that nitric acid is a
compound of nitrous gas and oxygen. The nature of nitrous gas itself
Lavoisier did not succeed in ascertaining. It passed with him for a
simple substance; but what he did ascertain enabled him to explain
the action of nitric acid on metals. When nitric acid is poured upon
a metal which it is capable of dissolving, copper for example, or
mercury, the oxygen of the acid unites to the metal, and converts into
an oxide, while the nitrous gas, the other constituent of the acid,
makes its escape in the gaseous form. The oxide combines with and is
dissolved by another portion of the acid which escapes decomposition.
It was discovered by Dr. Priestley, that when nitrous gas and oxygen
gas are mixed together in certain proportions, they instantly unite,
and are converted into nitrous acid. If this mixture be made over
water, the volume of the gases is instantly diminished, because the
nitrous acid formed loses its elasticity, and is absorbed by the
water. When nitrous gas is mixed with air containing oxygen gas, the
diminution of volume after mixture is greater the more oxygen gas is
present in the air. This induced Dr. Priestley to employ nitrous gas as
a test of the purity of common air. He mixed together equal volumes of
the nitrous gas and air to be examined, and he judged of the purity
of the air by the degree of condensation: the greater the diminution
of bulk, the greater did he consider the proportion of oxygen in the
air under examination to be. This method of proceeding was immediately
adopted by chemists and physicians; but there was a want of uniformity
in the mode of proceeding, and a considerable diversity in the results.
M. Lavoisier endeavoured to improve the process, in a paper inserted
in the Memoirs of the Academy, for 1782; but his method did not answer
the purpose intended: it was Mr. Cavendish that first pointed out an
accurate mode of testing air by means of nitrous gas, and who showed
that the proportions of oxygen and azotic gas in common air are
invariable.
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