Probably most lithographers still believe, as I did once, that the
etching with acids prepares the stone, and that the succeeding
application of gum merely increases this preparation. Countless
experiments have taught me that the exact reverse is true. Gum arabic
and a few other similar bodies are the true factors in preparation, and
the acids simply make the stone more receptive for them. Only sulphuric
acid, which changes the surface of the stone into gypsum, prepares it
without gum; but this is available only for a few intaglio methods.
The stone used for lithography consists mostly of limestone sated with
carbonic acid. Most acids, and even the salts, possess more affinity for
limestone than the carbonic acid, which latter is freed and escapes in
gaseous form as soon as another acid touches the stone. If aquafortis,
muriatic acid, vinegar, etc., is poured on the stone, there rise a
number of air blisters, which are nothing except the escaping carbonic
acid, and the applied fluid seems to boil, in degree according to its
strength. The boiling and bubbling last till the fluid has sated itself
with lime, after which it becomes still, and is impotent for further
etching.
The direct effect is the solution and destruction of parts of the
surface of the stone. If it has been coated in parts with a fatty
substance that resists the etching fluid, the places so coated are left
untouched, so that, when the stone is cleaned, all the fat-coated lines
and dots are in relief.
If the stone is coated with fatty matter, but not so thickly that the
acid is entirely resisted, it will pierce the covering and eat away more
or less of the stone. If the etching is continued or if the acid is
strong, the fatty coat will be destroyed entirely, the surface of the
stone will be clean, and ready for the ensuing preparation. The
preparation of the stone for pen drawings with oil or soap-water and
several aquatint methods, is based on this principle, that a very thin
coating of grease can be etched away partly or wholly, at will.
After eating away the surface of the stone the acids have the property
of giving it a fine polish.
Therefore if the stone has been covered with a design, and then etched
with an acid, it could be inked and printed many times, as long as it is
kept properly dampened and not too much pressure is used in applying the
ink. However, this could be done also with a thoroughly clean stone,
using only water, though the polish obtained from etching makes it much
easier. But this apparent preparation is not by any means sufficient to
print with certainty; and it becomes perfect only if the stone is coated
with a solution of gum arabic in water after being etched. If a plate
that has been merely etched and not treated with gum becomes dry during
printing, or even if too much pressure be used in applying ink or in
cleaning with the more or less smutty cleaning rags, it generally takes
color and smut which are extremely hard to remove.
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