We may assume, therefore, that the acids have the following effects on
the stone:--
(1) They will not attack the parts coated with grease.
(2) They will penetrate more or less if the fatty coating is only thin.
(3) Where they touch the stone they dissolve it and eat it away.
(4) They give it a polish that facilitates printing. This polish
disappears after a time on account of the cleaning with sponge or rag,
but is replaced by a new polish produced by this very means.
(5) They do not prevent the adherence of fatty material later, as soon
as the stone is dry, for which reason the parts prepared in the
beginning with acid and gum arabic must be prepared again by renewed
etching, to take the ink.
(6) Finally the acids have the property of giving to prepared stones
that have been used for impressions, a rough surface instead of a polish
when they are applied again, because they attack some parts more than
others, producing little pores with sharp edges which catch the ink.
This fact, as I will show more clearly later, makes necessary
extraordinary care if one wishes to clean prepared plates or correct
defects with new etching, because unskilled handling will often make
them worse.
II
THE ACIDS SPECIFICALLY
Nitric acid or aquafortis, muriatic acid, vinegar, tartaric acid, and
acid of wood sorrel, all have nearly similar effects, but aquafortis and
muriatic acid are used because of their greater cheapness.
Oil of vitriol or sulphuric acid, very much diluted with water, is
available for light but not for extensive etching, because it transforms
the surface of the stone into gypsum and deposits it again, so that
after that the acid cannot penetrate at all, or only partially. If a
part of vitriol, say diluted with twelve parts of water, is poured on a
cleanly ground stone, there ensues a violent action which, however, is
only brief. It might be supposed that the acid is sated with lime when
it ceases to act, but if it is moved to another part of the stone it
etches anew.
If the acid is washed from the stone and a woolen rag be used to rub it
after it is dry, it takes on a mirror-like polish. In this dry condition
it can be cleansed of color as easily as a copper plate, and if a stone
thus polished is engraved with a steel tool, it is possible to make
several impressions from it just as from copper. The polish is not
lasting, however, because the skin of gypsum is very thin. But it is a
useful method if it is desired to engrave the stone and ink it
frequently to see the effect.
Public-domain text, read in full here on John Shaqi.
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