The Library of Work and Play: Electricity and Its Everyday UsesWoodhull, John F. (John Francis)
Science
The Library of Work and Play: Electricity and Its Everyday Uses
Woodhull, John F. (John Francis)
Electricity -- Juvenile literature
It is conventional to speak of the electric current as flowing from the
carbon through the wire to the zinc, although every one has suspicions
that it may flow in the other direction or even that it may not flow
at all. It is conventional to designate any part of the circuit from
which the current comes as positive (+) to any other part toward
which it flows, this latter being considered negative to the former
and designated (-). The current is conceived of as making a complete
circuit, from carbon to zinc through the wire and from zinc to carbon
through the liquid. Hence, the binding post of the carbon rod is called
the + pole and that of the zinc is called the-pole, while the zinc rod
or plate beneath the surface of the fluid is called the + plate and
the carbon is called the-plate. The liquid is termed the electrolyte.
The sodium bichromate, introduced to cause the hydrogen to unite with
oxygen, is called an oxidizing agent or even a _depolarizing_ agent,
and hydrogen collecting upon the negative plate is said to polarize
the cell.
Hydrogen may be made to collect upon the carbon or negative plate until
the electric current reverses its direction. The hydrogen is said to be
more - than the zinc. If we connect the zinc and carbon rods with the
wires bringing an electric current from the dynamo we may make either
one positive as we choose, according to which is connected with the
positive wire. Hydrogen bubbles will collect upon whichever plate we
make the negative one.
When we send an electric current from the dynamo into this cell it
is called an electrolytic cell, and when it is used to generate an
electric current it is called a battery cell. In either case the
electrolyte is decomposed and put through a chemical change, though the
chemical action in one case is the reverse of that in the other, and
the direction of the electric current in one case is the reverse of
that in the other. For example let us consider the case of a zinc rod
and a carbon rod immersed in sulphuric acid and the external circuit
closed. The current passes as indicated by the arrows in Fig. 151, and
the chemical actions result in hydrogen leaving the sulphuric acid and
zinc taking its place, forming zinc sulphate. This is a white salt and
for purposes of this experiment must remain dissolved in water. So far
we have been considering a generator of electricity--a battery cell. We
may introduce something at _m_, say a motor, which will indicate that
an electric current is flowing. At length the cell ceases to generate
current and is, as we say, "run down." Suppose now we substitute a
dynamo in place of the motor in this circuit, connecting it so that the
carbon rod shall be its positive pole and the zinc its negative pole.
We now call this an electrolytic cell, (Fig. 152). The current will
decompose the zinc sulphate. The zinc will be coated upon the zinc rod
and hydrogen will be procured from the water present, of which it is a
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