The Library of Work and Play: Electricity and Its Everyday UsesWoodhull, John F. (John Francis)
Science
The Library of Work and Play: Electricity and Its Everyday Uses
Woodhull, John F. (John Francis)
Electricity -- Juvenile literature
constituent, to form again sulphuric acid as originally.
[Illustration: Fig. 151]
[Illustration: Fig. 152]
We shall thus restore the conditions which prevailed in the first case
as represented in Fig. 151. H_{2}SO_{4} is the chemist's designation
of sulphuric acid and ZnSO_{4} is his expression for zinc sulphate.
The experiment illustrates a storage battery so called. It might better
be called a chemical transformer.
It is wholly unnecessary that one rod be composed of zinc. If we
begin with both rods of carbon immersed in a solution of ZnSO_{4},
and send into this cell the dynamo current, the carbon which acts as
the negative pole will be coated with zinc in a short time, and we
shall have in effect a rod of zinc and one of carbon as before. After
a minute or two we may disconnect the generator and substitute in its
place a bell as indicator, and it will ring, showing that we have
transformed electrical energy into chemical energy which is now being
retransformed into electrical energy. We say that we store electricity
by this means, which is, however, no more true than that a farmer
stores his farm in the bank when he sells it and deposits the money
until he shall need it to buy another farm.
Here is a very beautiful blue salt. I will drop a few crystals of it
into a tumbler of water and dip in two carbon pencils connected to the
dynamo current, using between fifty and sixty ohms of resistance in
the circuit so as to have two amperes flowing. After a minute or two I
lift out the negative carbon and you see that it is well plated with
copper. The blue salt is copper sulphate. If we weigh the negative
carbon, both before and after the experiment, we shall find that copper
has been depositing at the rate of one ounce in twelve hours. If we
reduce the current one half, making it one ampere, it will deposit
copper at the rate of one ounce in twenty-four hours. One ampere will
separate three ounces of lead in a day from a solution of any lead
salt; it will separate .9 ounce of iron in a day from a solution of
any iron salt, and it will liberate from water, which is a compound of
hydrogen, one gallon of the gas in ten hours. The amount of chemical
action is a measure of the amount of electrical energy expended. Before
the present form of commercial wattmeter was devised electrolytic cells
were used to determine what the consumer's bill for electricity should
be each month. These chemical meters contained a solution of zinc
sulphate for the electrolyte and both the positive and the negative
plates were of zinc. While the current is passing, zinc from the
solution is coated upon the negative plate and zinc from the positive
plate takes its place in the solution, thus maintaining a constant
strength of solution.
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