Pasteur, Louis, 1822-1895; Scientists -- France -- Biography
After those days of national exaltation, Pasteur returned to his
crystals. He studied tartrates under the influence of certain ideas that
he himself liked to expound. Objects considered merely from the point of
view of form, may be divided into two great categories. First, those
objects which, placed before a mirror, give an image which can be
superposed to them: these have a symmetrical plan; secondly, those which
have an image which cannot be superposed to them: they are
dissymmetrical. A chair, for instance, is symmetrical, or a straight
flight of steps. But a spiral staircase is not symmetrical, its own
image cannot be laid over it. If it turns to the right, its image turns
to the left. In the same way the right hand cannot be superposed to the
left hand, a righthand glove does not fit a left hand, and a right hand
seen in a mirror gives the image of a left hand.
Pasteur noticed that the crystals of tartaric acid and the tartrates had
little faces, which had escaped even the profound observation of
Mitscherlich and La Provostaye. These faces, which only existed on one
half of the edges or similar angles, constituted what is called a
hemihedral form. When the crystal was placed before a glass the image
that appeared could not be superposed to the crystal; the comparison of
the two hands was applicable to it. Pasteur thought that this aspect of
the crystal might be an index of what existed within the molecules,
dissymmetry of form corresponding with molecular dissymmetry.
Mitscherlich had not perceived that his tartrate presented these little
faces, this dissymmetry, whilst his paratartrate was without them, was
in fact not hemihedral. Therefore, reasoned Pasteur, the deviation to
the right of the plane of polarization produced by tartrate and the
optical neutrality of paratartrates would be explained by a structural
law. The first part of these conclusions was confirmed; all the crystals
of tartrate proved to be hemihedral. But when Pasteur came to examine
the crystals of paratartrate, hoping to find none of them hemihedral, he
experienced a keen disappointment. The paratartrate also was hemihedral,
but the faces of some of the crystals were inclined to the right, and
those of others to the left. It then occurred to Pasteur to take up
these crystals one by one and sort them carefully, putting on one side
those which turned to the left, and on the other those which turned to
the right. He thought that by observing their respective solutions in
the polarizing apparatus, the two contrary hemihedral forms would give
two contrary deviations; and then, by mixing together an equal number of
each kind, as no doubt Mitscherlich had done, the resulting solution
would have no action upon light, the two equal and directly opposite
deviations exactly neutralizing each other.
Public-domain text, read in full here on John Shaqi.
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