The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
All the combinations analogous to the Voltaic pile had hitherto
consisted of a series containing, at least, _two_ metallic
bodies, (or one metal and charcoal,) and a stratum of fluid. Davy
discovered that an accumulation of galvanic energy, exactly similar
to that in the common pile, might be produced by the arrangement
of _single_ metallic plates with _different_ strata of fluids; so
that, instead of composing a battery with _two_ metals and _one_
fluid, he succeeded in constructing it with _one_ metal and _two_
fluids; provided always that oxidation, or some equivalent chemical
change, should proceed on one of the metallic surfaces only.
In describing these combinations of a single metal with two fluids,
he divides them into three classes, following in the arrangement
the order of time with regard to their discovery.
In the First Class, one side of the metallic plate is oxidated;
in the Second, a sulphuret is formed on one of its surfaces; and
in the Third, both sides are acted upon, the metal becoming a
_sulphuret_ on one of its surfaces, and an _oxide_ on the other.
The apparatus which he employed for these experiments is preserved
in the laboratory of the Royal Institution. It consists of a
trough, containing grooves capable of receiving the edges of the
different plates necessary for the arrangement, one half of which
are composed of horn, the other half of some one metal.
When the apparatus was used, the cells were filled, in the galvanic
order, with the different solutions, according to the class of the
combination, and connected in pairs with each other by slips of
moistened cloth carried over the non-conducting plates.
At the meeting of the Royal Society, following that on which the
above interesting facts were communicated, Dr. Wollaston presented
a memoir of considerable importance, entitled, "Experiments on
the Chemical Production and agency of Electricity;" in which he
strongly advocates the truth of that theory which recognises
metallic oxidation as the _primary_ cause of the Voltaic phenomena.
This paper is also farther important as it proves, by most
ingeniously devised experiments, not only the similarity of the
means by which both common and galvanic electricity are excited,
but also the resemblance existing between their effects; showing,
in fact, that they are both essentially the same, and confirming
the opinion, that all the apparent differences may depend upon
differences in intensity and quantity.
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