The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
Acting upon this principle, Dr. Wollaston succeeded in producing a
very close imitation of the chemical action of galvanism by common
electricity; such, for example, as the decomposition of water, and
other effects of oxidation and deoxidation.[60] In the prosecution
of this train of research, he displays, in a very striking
manner, that attention to minute arrangement which so remarkably
characterised all his manipulations. I particularly allude to
the expedients by which he reduced the extremity of a gold wire,
in order to apportion the strength of the electric charge to the
quantity of water submitted to its influence.
[60] M. Bonijol of Geneva has lately succeeded in effecting
the decomposition of _Potash_ and the _Chloride of Silver_ by
ordinary electricity. His process consists in placing these
substances in a very narrow glass tube, and in then passing a
series of electric sparks from the ordinary machine through
them. The electricity was conducted into the tube by means of
two metallic wires fixed into the ends. When a quick succession
of electric sparks had taken place for about five or ten
minutes, the tube containing chloride of silver was found to
contain reduced silver; and when potash had been submitted to
the electric current, then the Potassium was seen to take fire
as it was produced. The same philosopher has likewise contrived
to decompose water by atmospheric electricity. The electricity,
in this case, is collected from the atmosphere by means of a
very fine point fixed at the extremity of an insulated rod; the
latter is connected with the apparatus, in which the water is to
be decomposed, by a metallic wire, of which the diameter does
not exceed 1-50th of an inch. In this way the decomposition of
the water proceeds in a continuous and rapid manner, although
the atmospheric electricity be not strong. Stormy weather, it is
said, is quite sufficient for the purpose.--_Bib. Univers._ 1830,
p. 213. and _Royal Institution Journal_, No. 2.
Although it is now very generally admitted, that the chemical
agency of the fluids upon the metals employed is highly essential
to the maintenance of Voltaic action, there still remains
considerable doubt as to how far we are entitled to regard it as
the first in the order of phenomena.
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