The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
At a later period of his researches, Davy suggested as a correction,
or rather modification, of the theory of Volta, that the
electro-motion produced by the contact of the metals might
be the primary cause of the chemical changes; and that such
changes were in no other way efficient, than in restoring the
electric equilibrium thus disturbed: it was farther held, that
this equilibrium could not be permanent, that it could in fact be
only momentary; since, in consequence of the imperfect conducting
power of the interposed fluid, the zinc and copper-plates, by their
electro-motive power, would again assume their opposite states
of electricity; and that these alternate changes would occur,
as long as any of the fluid remained undecomposed. In a Voltaic
arrangement, then, there would appear to exist, if the expression
may be allowed, a kind of electrical seesaw; the apposition of
the metals destroying the equilibrium, and the resulting chemical
changes again restoring it. It has, however, been very justly
observed, that the application of electricity, as an instrument
of chemical decomposition, has most fortunately no connexion with
such theories, and that the study of its effects may be carried on
without reference to any hypothetical notions concerning the origin
of the phenomena.
An interval of nearly five years had elapsed between the first
communication which Davy made on this subject, and the Bakerian
lecture which is immediately to be considered. During this period
several new facts had been added by different experimentalists, but
they were scattered, disjointed, and totally unconnected with each
other by any rational analogies.
The constant appearance of acid and alkaline matter in pure water,
when submitted to the influence of the Voltaic pile, gave rise
to the most extravagant speculations and discordant hypotheses.
Various statements were made, both in Italy and England, respecting
the _generation_ of muriatic acid, and that of the fixed alkalies,
under these circumstances. Mr. Sylvester affirmed, that if two
separate portions of water were electrised out of the contact of
substances containing alkaline or acid matter, acid and alkali
would, nevertheless, be produced.
Some philosophers sought to explain the phenomenon from the salts
contained in the fluids of the trough, which they imagined might,
by some unsuspected channel, find their way into the water under
examination. Others believed that they were actually _generated_
by the union of the electric fluid with the water, or with one or
both of its elements; so that, up to the time of Davy's masterly
researches, the subject was involved in the greatest obscurity; and
whether the saline matter was liberated from unknown combinations,
or at once formed by the union of its elements, was a question upon
which the greatest chemists entertained different opinions.
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