The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
It occurred to him, that the nascent oxygen and hydrogen of the
water might respectively combine with a portion of the nitrogen
of the common air, which is constantly dissolved in that fluid;
but if this were the case, how did it happen that the production
of nitrous acid was progressive, while that of the alkali was
limited? The experiments of Dr. Priestley, on the absorption of
gases by water, at once suggested themselves to his mind as being
capable of solving this last difficulty; for that distinguished
philosopher had shown, that hydrogen, during its solution in
water, expelled the nitrogen, whereas oxygen and nitrogen were
capable of coexisting in a state of solution in that fluid. It was,
however, necessary to confirm the truth of this explanation by
experiment, and he accordingly introduced the two cones of gold,
containing purified water, under the receiver of an air-pump; the
exhaustion was effected, and the Voltaic pile brought to act upon
the water thus circumstanced; after eighteen hours the result was
examined, when the water in the negative cone produced no effect
upon prepared litmus, but that in the positive vessel did give it a
tinge of red barely perceptible.
Had his series of experiments terminated here, the truth of his
conclusions would have been established by the comparatively
small proportion of acid formed in this latter experiment; but he
determined to repeat it under circumstances, if possible, still
more unexceptionable and conclusive. Having, therefore, arranged
the apparatus as before, he exhausted the receiver, and then filled
it with hydrogen gas from a convenient air-holder; he made even a
second exhaustion, to ensure the highest accuracy, and then again
introduced carefully prepared hydrogen. The Voltaic process was
continued during twenty-four hours, and at the end of that period
it was found that neither the water in the positive nor in the
negative vessels altered the tint of litmus in the slightest degree.
Thus did he succeed in exposing the three great sources of fallacy
which had so long misled chemists, with regard to the generation
of acid and alkaline matter in Voltaic experiments, viz.--The
impurities of the vessels--the foreign matter contained in the
water--and the compounds generated by the combination of the
nitrogen of atmospheric air with the elements evolved from water;
and thus did he establish, by an unbroken chain of incontrovertible
evidence, the important truth, that "water, chemically pure, is
decomposed by electricity into gaseous matter alone--into oxygen
and hydrogen."
Out of the foregoing train of research very naturally sprang the
consideration of the _decomposing agencies of Electricity_. It had
been constantly observed, that, in all electrical changes connected
with the presence of acid and alkaline matter, the former uniformly
collected around the positive, and the latter around the negative
surface of the apparatus.
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