The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
In one of the earliest experiments, Davy had also noticed that
glass underwent decomposition, and that its alkali always passed to
the negative surface. He was, therefore, led to enquire whether,
through electrical agency, different solid earthy compounds,
insoluble, or soluble with difficulty in water, might not be made
to undergo a similar decomposition. We shall find that the results
of the trials were decisive and satisfactory. For conducting
experiments of this description, he hit upon the happy expedient
of constructing the cups with the materials which he wished to
submit to experiment, and then by introducing water into them, and
forming the necessary connexion by means of asbestus, he completed
the Voltaic circuit. In this manner he submitted to experiment
_sulphate of lime_, _sulphate of strontia_, _fluate of lime_,
_sulphate of baryta_, &c. and with analogous results; the acid
element in each case passing to the positive, and the earthy base
to the negative cup.
As, in the above experiments, the bodies under examination were
presented in considerable masses, and exposed large surfaces to
the electric action, it became necessary to enquire whether minute
portions of acid and alkaline matter could, by the same agency, be
disengaged from solid combinations. This point was very readily
elucidated. A piece of fine grained basalt, which, by a previous
analysis, had been found to contain 3·5 per cent. of soda, nearly
·5 of muriatic acid, and fifteen parts of lime, having been
divided into two properly-shaped pieces, and a cavity, capable
of containing twelve grains of water, been drilled in each, was
submitted, as in former experiments, to the action of the pile. At
the end of ten hours, the result was examined with care, when it
appeared that the positively electrified water had the strong smell
of oxymuriatic acid, and copiously precipitated nitrate of silver;
while that which was negative affected turmeric, and left by
evaporation a residuum which appeared to consist of lime and soda.
A part of a specimen of compact zeolite from the Giants' Causeway,
and vitreous lava from Ætna, were each treated in a similar manner,
and with results equally satisfactory.
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