The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
In the farther prosecution of the enquiry, Davy discovered a still
more extraordinary series of facts. In the first place, he found
that the contact of the saline solution with a metallic surface was
not in the least necessary for its decomposition. He introduced
purified water into two glass tubes, and connected with them, by
means of amianthus, a vessel containing a solution of muriate of
potash. In this case, the saline matter was distant from each of
the wires at least two-thirds of an inch; and yet alkaline matter
soon appeared in one tube, and acid matter in the other; and in
sixteen hours moderately strong solutions of potash and muriatic
acid had been formed.
The discovery of this fact became the key to that of others. He
very naturally proceeded to enquire into the progress of the
transfer, and into the course of the acid and alkaline elements;
when, by the use of litmus and turmeric, he arrived at the
following conclusion,--that acids and alkalies, during their
electrical transference, passed through water containing vegetable
colours without effecting in them any change. From which we are led
to the consideration of the fourth division of the subject, viz.
"On the Passage of Acids, Alkalies, and other Substances, through
various attracting Chemical Menstrua, by Electricity."
As soon as it was discovered that a power generated by the Voltaic
pile was capable of destroying elective affinity in the vicinity
of the metallic points, it seemed reasonable to suppose, that
the same power might also destroy it, or at least suspend its
operation, throughout the whole of the circuit. The truth of such
a supposition was at once placed beyond all doubt by the following
very striking experiment.
Three tubes, the first containing a solution of _sulphate of
potash_, the second a weak solution of _ammonia_, and the third,
_pure water_, each being connected with the other in the usual
manner by amianthus, were arranged in relation to the pile, as
follow:--the _sulphate of potash_ was placed in contact with the
negatively electrified point, the _pure water_ with the positively
electrified point, while the solution of _ammonia_ was made the
middle link of the conducting chain; so that no sulphuric acid
could pass to the positive point in the distilled water, without
passing through the ammoniacal solution.
In less than five minutes after the electric current had been
completed, it was found, by means of litmus paper, that acid was
in the act of collecting around the positive point; and in half an
hour the result was sufficiently distinct for accurate examination.
Other experiments were made with a solution of lime, and with weak
solutions of potash and soda, and the results were analogous.
Muriatic acid, from muriate of soda, and nitric acid, from nitrate
of potash, were also transmitted through concentrated alkaline
menstrua, under similar circumstances, and with like effects.
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