The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
Davy also made several experiments on the transition of alkaline
and acid matter, through different neutro-saline solutions, the
results of which were exactly such as theory would have anticipated.
In conducting, however, these experiments of electrical
transference, there would appear to be one condition essential to
their success, viz. that the solution contained in the intermediate
vessel should not be capable of forming an insoluble compound with
the substance transmitted through it: thus, for example, Davy
found that _strontia_ and _baryta_ passed, like the other alkaline
substances, very readily through muriatic and nitric acids;
and _vice versâ_, that these acids passed with equal facility
through aqueous solutions of the earths in question; but when it
was attempted to pass _sulphuric_ acid through the same earthy
solutions, or to pass the earths through the sulphuric acid, that
then the results were of a very different character: the sulphuric
acid, in its passage through the barytic solution, was arrested in
its progress by the earthy body, and falling down as an insoluble
compound with it, was carried out of the sphere of the electrical
action, by which the power of transfer was destroyed. The same
phenomena occurred whenever he attempted to pass muriatic acid
through a solution of sulphate of silver. We now come to the next
division--viz. "Some general Observations on these Phenomena, and
on the mode of Decomposition and Transition."
Davy considers that it will be a general expression of the facts
relating to the changes and transitions by electricity, to say,
that "hydrogen, the alkaline substances, the metals, and certain
oxides, are attracted by negatively electrified, and repelled by
positively electrified metallic surfaces; and on the contrary, that
oxygen and acid substances are attracted by positively electrified,
and repelled by negatively electrified metallic surfaces."
And moreover, that these "attractive and repulsive forces are
sufficiently energetic to destroy or suspend the usual operation of
elective affinity."
Public-domain text, read in full here on John Shaqi.
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