The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
The history of these researches into the nature of the ammoniacal
element concludes the lecture of which I have endeavoured to
give an outline. The subject of the amalgam is still involved in
mystery: if we suppose with Davy, that a substance, which forms
so perfect an amalgam with mercury, must of necessity be metallic
in its own nature, we cannot but conclude either that hydrogen
and nitrogen are both metals in the aëriform state, at the usual
temperatures of the atmosphere--bodies, for example, of the
same character as zinc and quicksilver would be at the heat of
ignition--or, that these gases are oxides in their common form,
but which become metallized by deoxidation--or, that they are
simple bodies, not metallic in their own nature, but capable of
composing a metal in their deoxygenated, and an alkali in their
oxygenated, state.
Before we venture, however, to entertain any opinions so
extravagant in their nature, and so wholly unsupported by analogy,
it would be well to enquire how far the change, which ammonia
and mercury undergo by Voltaic action, really merits the name of
amalgamation. Several chemists of the present day are inclined to
refer this change of form to a purely mechanical cause, by which
the particles of the metal become separated, and converted, as it
were, into a kind of _froth_ by the operation.[84]
[84] The late interesting experiments of Mr. Daniell "on the
action of Mercury on different Metals," which have been recently
published in the first number of a new series of the Journal
of the Royal Institution, appear to throw much light upon this
subject. By agitating a few grains of spongy platinum with
mercury in water acidified with acetic acid, he obtained an
amalgam of the consistence of soft butter, which retained its
consistence for many weeks, and greatly resembled that formed by
the electrization of mercury in contact with ammonia. When the
amalgam was laid upon filtering paper, the moisture was gradually
absorbed and evaporated, and the mercury returned to a fluid
state. By a more refined experiment, Mr. Daniell ascertained that
the process was accompanied by the evolution of hydrogen gas;
whence he very fairly concludes, that, when minutely divided,
platinum is agitated with mercury, and moisture is present, an
electrical action takes place, which, when heightened by the
addition of a diluted acid, or the solution of a neutral salt, is
sufficiently energetic to decompose water and evolve hydrogen:
the oxygen at the same time combines with the mercury, and a
solution is effected by the acetic acid, which its unassisted
affinity could not have produced. "It also appears," continues
Mr. Daniell, "that this electrical action communicates an
adhesive attraction to the particles of the metal, by which
the particles of liquid and aëriform bodies are entangled and
retained, a kind of _frothy_ compound formed, and the fluidity
of the mercury destroyed.
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